{"title":"Trans-to-cis isomerization of a platinum(II) complex with two triphosphine ligands via coordination with gold(I) ions","authors":"Kazuki Nagasato, Taichi Baba, Hayato Soma, Nobuto Yoshinari","doi":"10.1007/s10847-024-01228-2","DOIUrl":null,"url":null,"abstract":"<div><p>The reaction of a square-planar platinum(II) complex containing two bis(2-diphenylphosphinoethyl)phenylphosphine (triphos), [Pt(triphos)<sub>2</sub>](NO<sub>3</sub>)<sub>2</sub>, with [Au(tu)<sub>2</sub>]Cl (tu = thiourea) gave a new trinuclear Au<sup>I</sup><sub>2</sub>Pt<sup>II</sup> complex, [Pt(triphos)<sub>2</sub>{Au(tu)}<sub>2</sub>]Cl<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>, through Au-P coordination. While the [Pt(triphos)<sub>2</sub>]<sup>2+</sup> unit in [Pt(triphos)<sub>2</sub>](NO<sub>3</sub>)<sub>2</sub> adopted the trans-meso configuration, only the cis-racemic isomer was observed for [Pt(triphos)<sub>2</sub>{Au(tu)}<sub>2</sub>]Cl<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>. <sup>31</sup>P NMR spectroscopy indicated rapid equilibrium among the possible isomers of [Pt(triphos)<sub>2</sub>]<sup>2+</sup>, which facilitated the trans-to-cis transformation at the Pt<sup>II</sup> center in this system. Additionally, we observed that this structural transformation led to an increase in the emission intensity.</p></div>","PeriodicalId":638,"journal":{"name":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","volume":"104 5-6","pages":"257 - 268"},"PeriodicalIF":2.3000,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10847-024-01228-2.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10847-024-01228-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Agricultural and Biological Sciences","Score":null,"Total":0}
引用次数: 0
Abstract
The reaction of a square-planar platinum(II) complex containing two bis(2-diphenylphosphinoethyl)phenylphosphine (triphos), [Pt(triphos)2](NO3)2, with [Au(tu)2]Cl (tu = thiourea) gave a new trinuclear AuI2PtII complex, [Pt(triphos)2{Au(tu)}2]Cl2(NO3)2, through Au-P coordination. While the [Pt(triphos)2]2+ unit in [Pt(triphos)2](NO3)2 adopted the trans-meso configuration, only the cis-racemic isomer was observed for [Pt(triphos)2{Au(tu)}2]Cl2(NO3)2. 31P NMR spectroscopy indicated rapid equilibrium among the possible isomers of [Pt(triphos)2]2+, which facilitated the trans-to-cis transformation at the PtII center in this system. Additionally, we observed that this structural transformation led to an increase in the emission intensity.
期刊介绍:
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.