Investigating the Effects of Urea-Zinc Sulfate-L Phenylalanine on the Corrosion Inhibition of Mild Steel Exposed to pH-4 Sulfuric Acid

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-13 DOI:10.2174/0115734110296231240501170801
M.B Geetha, Rajesh Nithyanandam, Jenish Soosai, S.S. Rajendran
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Abstract

Background: Corrosion of mild steel is a risk to material and stability. The practice of corrosion inhibitors is a cost-effective corrosion modification method for mild steel. Organic inhibitors rich in electrons might have an excellent ability to prevent corrosion. This study aims to assess the inhibitory effect of the mixture of Urea, Zinc Sulfate, and L-Phenylalanine, which has a high electron density Methods: MS corrosion was experimentally performed using H2SO4 at a pH of 4. Different gravimetric and conventional techniques, such as polarization, AC impedance AFM, UV, and fluorescence, were used to examine the studied data. Results: According to gravimetric measurements, this combination produced 93% effective inhibition. The findings of the impedance test proved that the mixture of inhibitors that was adsorbed on the metal surface effectively prevented corrosion. Conclusion: Likewise, according to the Polarization measurements, the inhibitor exhibits mixed-type performance with significant cathodic activity. UV, Fluorescence, and AFM findings showed that MS corrosion was suppressed because the inhibitor molecule adhered to the metal's surface and reduced.
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研究尿素硫酸锌-苯丙氨酸对暴露于 pH-4 硫酸中的低碳钢的缓蚀效果
背景:低碳钢的腐蚀对材料和稳定性都有风险。使用缓蚀剂是一种经济有效的低碳钢腐蚀改性方法。富含电子的有机缓蚀剂可能具有出色的防腐蚀能力。本研究旨在评估尿素、硫酸锌和具有高电子密度方法的 L-苯丙氨酸混合物的缓蚀效果:使用极化、交流阻抗原子力显微镜、紫外线和荧光等不同的重量测量法和常规技术来检测研究数据。研究结果重力测量结果显示,该组合的有效抑制率为 93%。阻抗测试结果证明,吸附在金属表面的抑制剂混合物能有效防止腐蚀。结论同样,根据极化测量结果,该抑制剂表现出混合型性能,具有显著的阴极活性。紫外线、荧光和原子力显微镜研究结果表明,由于抑制剂分子附着在金属表面并减少,MS 腐蚀被抑制。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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