Investigating ion irradiation effects for modifying optical properties of CA/PANI films

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-05-16 DOI:10.1680/jsuin.24.00014
Reem Altuijri, E Abdeltwab, Nuha Al-Harbi, A. Atta, M. M. Abdel-Hamid, A. Henaish
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Abstract

In this study, flexible CA/PANI films, consisting of polyaniline (PANI) and cellulose acetate (CA), were created via a solution cast production process. Then, these films were irradiated using of handmade cold cathode ion device with argon fluence of 2x1017, 4x1017, and 6x1017 ions/cm2. The SRIM program was used to investigate the ion penetration depth, ion distribution in the composite and the energy stopping loss. Moreover, the FTIR technique was used to identify the changes of the treated CA/PANI. The UV-Vis technique was used to show the impact of argon beam on the optical characteristics of CA/PANI composite film. The oscillation energy (E0) dropped from 8.88 for CA/PANI to 7.83, 6.42, and 5.19 eV after exposed to 2x1017, 4x1017, and 6x1017 ions/cm2. The results showed that the ion altered the optical characteristics of the CA/PANI samples, which allow for applied these irradiated CA/PANI films in optoelectronic devices.
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研究离子辐照对改变 CA/PANI 薄膜光学特性的影响
在这项研究中,通过溶液浇铸生产工艺制作了由聚苯胺(PANI)和醋酸纤维素(CA)组成的柔性 CA/PANI 薄膜。然后,使用手工制作的冷阴极离子装置,以 2x1017、4x1017 和 6x1017 离子/cm2 的氩离子流对这些薄膜进行辐照。利用 SRIM 程序研究了离子穿透深度、复合材料中的离子分布以及能量阻挡损失。此外,还利用傅立叶变换红外技术确定了经处理的 CA/PANI 的变化。紫外可见光技术用于显示氩气束对 CA/PANI 复合薄膜光学特性的影响。在暴露于 2x1017、4x1017 和 6x1017 离子/cm2 后,CA/PANI 的振荡能 (E0) 从 8.88 下降到 7.83、6.42 和 5.19 eV。结果表明,离子改变了 CA/PANI 样品的光学特性,因此可以将这些经过辐照的 CA/PANI 薄膜应用于光电设备中。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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