{"title":"Redox-Neutral 1,2-Dicarbonfunctionlization of 1,3-Butadiene by Merging Decatungstate and Chromium Catalysis","authors":"D. Ding, Pu-Sheng Wang","doi":"10.1055/a-2328-3037","DOIUrl":null,"url":null,"abstract":"Homoallylic alcohol is a significantly useful intermediate in organic synthesis. Here we establish a three-component NHK-type reaction of 1,3-butadiene, aldehydes and aliphatic C–H partners by merging decatungstate and chromium catalysis, enabling a modular, redox-neutral and atom-economic strategy to access a diverse range of homoallylic alcohols.","PeriodicalId":510101,"journal":{"name":"Synthesis","volume":"136 27","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2328-3037","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Homoallylic alcohol is a significantly useful intermediate in organic synthesis. Here we establish a three-component NHK-type reaction of 1,3-butadiene, aldehydes and aliphatic C–H partners by merging decatungstate and chromium catalysis, enabling a modular, redox-neutral and atom-economic strategy to access a diverse range of homoallylic alcohols.
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