Characterization and optical studies of flexible methylcellulose/titanium dioxide nanomaterials

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-13 DOI:10.15251/djnb.2024.192.629
H. Al-Yousef, B. M. Alotaibi, A. Atta, E. Abdeltwab, M. M. Abdelhamied
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Abstract

In this work, flexible MC/TiO2 polymer composites were successfully manufactured using the solution casting method to enhance their implementations in optical applications. The composite consisting of methylcellulose (MC) with different concentrations of titanium dioxide (TiO2) of 3%, 6%, and 9%. The successful fabrication of MC/TiO2 films were confirmed through XRD characterization. The addition of TiO2 enhances the refractive indices (n0), it increased from 1.014 for MC respectively to 1.025,1.032 and 1.045 for MC/3%TiO2, MC/6%TiO2 and MC/9%TiO2. The MC exhibited an oscillation energy of 6.86 eV, changed respectively to 5.25 eV, 4.96 eV, and 4.59 eV. Furthermore, the dispersion energy values were observed to be 0.18 eV for MC, respectively changed to 0.23 eV, 0.26 eV, and 0.35 eV, for MC/3%TiO2, MC/6%TiO2 and MC/9%TiO2. The data clearly indicates the introduction of TiO2 into the MC polymer results in a modification of its optical characteristics, to be applicable in different fields of optoelectronics.
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柔性甲基纤维素/二氧化钛纳米材料的特性和光学研究
在这项研究中,利用溶液浇铸法成功制造了柔性 MC/TiO2 聚合物,以提高其在光学领域的应用。复合材料由甲基纤维素(MC)和不同浓度的二氧化钛(TiO2)(3%、6% 和 9%)组成。通过 XRD 表征证实了 MC/TiO2 薄膜的成功制备。二氧化钛的加入提高了折射率(n0),MC/3%TiO2、MC/6%TiO2 和 MC/9%TiO2 的折射率分别从 1.014 提高到 1.025、1.032 和 1.045。MC 的振荡能为 6.86 eV,分别变为 5.25 eV、4.96 eV 和 4.59 eV。此外,观察到 MC 的色散能值为 0.18 eV,而 MC/3%TiO2、MC/6%TiO2 和 MC/9%TiO2 的色散能值分别变为 0.23 eV、0.26 eV 和 0.35 eV。这些数据清楚地表明,在 MC 聚合物中引入 TiO2 可改变其光学特性,从而适用于不同的光电领域。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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