Nanosilica from canary seed husk for corrosion protection of structural steel

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-09 DOI:10.1002/vjch.202300264
U. León-Silva, M. E. Nicho, L. Cajero‐Sotelo, C. Castro‐Guerrero, Jesús Escobedo‐Alatorre, M. R. Díaz‐Guillén
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Abstract

An alternative technique is presented for the corrosion protection of the A36 structural steel (A36SS) in acid medium (H2SO4) using silica obtained from canary seed husk (CSH). The silica was obtained in a solid amorphous state with a particle size of 10–22 nm. The anticorrosive properties of nanosilica (NS) were studied using potentiodynamic polarization (PDP), linear polarization resistance (LPR), and electrochemical impedance spectroscopy (EIS). Before carrying out the corrosion tests, the A36SS was subjected to a treatment with NaOH solution without and with the presence of NS. The A36SS treated with NS presented the lowest current density values and the noblest corrosion potential values, indicating that the corrosion rate decreased. The surface morphological study of the tested systems using SEM/EDS showed that the NS‐treated A36SS had a more efficient physical barrier against corrosive species.
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金丝雀籽壳纳米二氧化硅用于结构钢的防腐保护
本文介绍了一种利用从金丝雀籽壳(CSH)中提取的二氧化硅在酸性介质(H2SO4)中对 A36 结构钢(A36SS)进行腐蚀保护的替代技术。白炭黑为无定形固体,粒径为 10-22 纳米。使用电位极化(PDP)、线性极化电阻(LPR)和电化学阻抗光谱(EIS)对纳米二氧化硅(NS)的防腐特性进行了研究。在进行腐蚀测试之前,先用 NaOH 溶液对 A36SS 进行了处理,其中包括不添加 NS 和添加了 NS 的情况。经 NS 处理的 A36SS 的电流密度值最低,腐蚀电位值最高,表明腐蚀速率降低。使用 SEM/EDS 对测试系统进行的表面形态研究表明,经过 NS 处理的 A36SS 对腐蚀物种具有更有效的物理屏障作用。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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