An Examination of Bronze Vessel Technology in the Unified Silla Period: Case Study on the Bronzes Excavated from Gwanbuk-ri Site in Buyeo

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-05 DOI:10.3365/kjmm.2024.62.5.393
So Jin Kim, Woo Rin Han, Young Do Kim
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Abstract

Archaeological excavations in Buyeo had revealed Bronze vessels interred within a hole in the building at the Gwanbuk-ri site. These bronze vessels are dated to the Unified silla period (9-10th centuries). To identify the bronze vessels’ manufacturing technology, metallurgical analyses were carried out using Optical Microscopy, SEM-EDS and EPMA. The results allowed a reconstruction of the manufacturing process of bronze vessels in the Unified silla. It proved that bronze vessels were manufactured with Cu-Sn alloy with varying tin contents, which may be related to the application of uncontrolled procedures in making the bronze alloys. Also a casting process was used to shape the bronze vessels and the strength and hardness of the container were improved through a quenching process. Twins were observed in one of the samples, so it was assumed that hot working had been attempted. Non-metallic inclusions in bronze vessels have circular or polygonal shapes, and Cu and S were detected. The presence of Cu-S inclusions showed the probable use of copper sulphide ores for metal production and smelting. Se and Te in the inclusions of the bronze vessels show that the copper ore is different. From the results of metallurgical analyses of bronze vessels excavated from other regions of the same era, casting and quenching treatments were confirmed, and the sequential relationship of the technological system was revealed.
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统一新罗时期青铜器技术考察:扶餘關北里遺址出土青銅器的個案研究
在扶餘进行的考古发掘中,发现了埋藏在观北里遗址建筑孔洞中的青铜器。这些青铜器的年代为统一新罗时期(9-10 世纪)。为了确定青铜器的制造技术,使用光学显微镜、扫描电镜-电子显微镜和 EPMA 进行了冶金分析。分析结果有助于重建统一新罗时期青铜器的制造过程。结果表明,青铜器是用含锡量不同的铜锡合金制造的,这可能与制造青铜合金时采用了不受控的程序有关。此外,青铜器还采用了铸造工艺,并通过淬火工艺提高了容器的强度和硬度。在其中一个样品中观察到了孪晶,因此推测曾尝试过热加工。青铜容器中的非金属夹杂物呈圆形或多边形,并检测到铜和 S。Cu-S夹杂物的存在表明可能使用了硫化铜矿石进行金属生产和冶炼。青铜器夹杂物中的 Se 和 Te 表明铜矿石是不同的。从同一时代其他地区出土的青铜器的冶金分析结果来看,铸造和淬火处理得到了证实,并揭示了工艺系统的先后关系。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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