Surface modified molybdenum disulfide nanosheets for corrosion resistance improvement on polyurethane coatings

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-05-03 DOI:10.1515/corrrev-2023-0119
Guilin Zhou, Jingchuan Wang, Wenjie Cheng, Hui Nan, Xiaochong Zhao, Haomin Wei, Caihong Xue, Yuehua Ma, Pan Yang
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Abstract

Organic–inorganic hybrid coating has been applied on metallic corrosion protection effectively. Molybdenum disulfide (MoS2) nanosheets with graphene-like two-dimensional lamellar structure were an anticorrosion inorganic additive, rendering the organic coating better corrosion resistant. However, the aggregation and poor solubility are still current issues that should be addressed. Functionalization MoS2 nanosheets with surface modified by polydopamine (PDA) and silane coupling agent (KH560) were prepared in polyurethane (PU) composite coatings to obtain dense and intact multilayer network structure coatings for corrosion protection. KH560-PDA-MoS2/PU coating with crosslinked polymer network structure has a high impedance modulus, large contact angle, and strong hydrophobicity. The coating meets the national technical standards for salt spray testing and nitric acid (HNO3) titration testing, demonstrating excellent corrosion resistance.
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用于改善聚氨酯涂层耐腐蚀性能的表面改性二硫化钼纳米片
有机-无机混合涂层已被有效地应用于金属防腐。二硫化钼(MoS2)纳米片具有类似石墨烯的二维片状结构,是一种防腐无机添加剂,使有机涂层具有更好的防腐性能。然而,聚集和溶解性差仍然是当前亟待解决的问题。在聚氨酯(PU)复合涂层中制备了表面经聚多巴胺(PDA)和硅烷偶联剂(KH560)改性的功能化 MoS2 纳米片,从而获得致密完整的多层网络结构涂层,用于防腐。具有交联聚合物网络结构的 KH560-PDA-MoS2/PU 涂层阻抗模量高、接触角大、疏水性强。该涂层符合盐雾测试和硝酸(HNO3)滴定测试的国家技术标准,具有优异的耐腐蚀性能。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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