Ir-Catalyzed ortho-C-H Borylation of Aromatic C(sp2)-H Bonds of Carbocyclic Compounds Assisted by N-Bearing Directing Groups

Reactions Pub Date : 2024-05-01 DOI:10.3390/reactions5020016
Hamad H. Al Mamari
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Abstract

C-H borylation is a powerful strategy for the construction of C-B bonds due to the synthetic versatility of C-B bonds. Various transition metals affect the powerful functionalization of C-H bonds, of which Ir is the most common. Substrate-directed methods have enabled directed Ir-catalyzed C-H borylation at the ortho position. Amongst the powerful directing groups in Ir-catalyzed C-H borylation are N-containing carbocyclic systems. This review covers substrate-directed Ir-catalyzed ortho-C-H borylation of aromatic C(sp2)-H bonds in N-containing carbocyclic compounds, such as anilines, amides, benzyl amines, hydrazones, and triazines.
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含 N 引导基团辅助的 Ir 催化羰环化合物芳香族 C(sp2)-H 键的正交-C-H 玻里化反应
由于 C-B 键的合成多样性,C-H 硼赖化是构建 C-B 键的一种强有力的策略。各种过渡金属都会影响 C-H 键的强功能化,其中 Ir 是最常见的一种。底物定向方法实现了铱催化的正交位置 C-H 硼酰化。在 Ir 催化的 C-H 玻里化反应中,含有 N 的碳环系统是强大的定向基团。本综述涉及底物定向 Ir 催化的含 N 碳环化合物(如苯胺、酰胺、苄胺、肼和三嗪)中芳香族 C(sp2)-H 键的正位 C-H 玻里化反应。
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