The application of palladium catalysts in catalyzing the hydrogenolysis of N-benzyl compounds

IF 4.7 2区化学 Q2 CHEMISTRY, PHYSICAL Applied Catalysis A: General Pub Date : 2024-05-17 DOI:10.1016/j.apcata.2024.119802

Shuyuan Lou, Jianhong Jin, Qingtao Wang, Xiaoliang Xu, Qunfeng Zhang, Xiaonian Li

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Abstract

The current review offers a comprehensive analysis of the catalytic N-benzyl hydrogenolysis debenzylation reaction, encompassing an examination of the catalytic mechanism and kinetic characteristics. Among the various catalysts employed in C−N hydrolysis, the supported palladium catalyst stands out as the most frequently employed catalyst. This review thoroughly elucidates the utilization of palladium catalyst in N-benzyl catalytic hydrogenolysis, providing insights into its activity, selectivity, and stability concerning support materials, cocatalysts, solvents, and pH conditions. These findings yield valuable insights for optimizing catalyst design and reaction conditions. Additionally, we briefly introduce the applications of other metallic catalysts such as nickel and platinum in catalyzing N-benzyl hydrogenolysis reactions. This provides valuable guidance for advancing our understanding of the hydrogenolysis reaction mechanisms, enhancing catalyst performance, and developing novel catalytic agents.

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钯催化剂在催化 N-苄基化合物氢解中的应用

本综述全面分析了催化 N-苄基氢解脱苄基反应，包括对催化机理和动力学特性的研究。在 C-N 水解反应中使用的各种催化剂中，支撑钯催化剂是最常用的催化剂。本综述全面阐释了钯催化剂在 N-苄基催化加氢分解中的应用，深入探讨了钯催化剂在支撑材料、助催化剂、溶剂和 pH 值条件下的活性、选择性和稳定性。这些发现为优化催化剂设计和反应条件提供了宝贵的见解。此外，我们还简要介绍了镍和铂等其他金属催化剂在催化 N-苄基氢解反应中的应用。这为我们进一步了解氢解反应机理、提高催化剂性能和开发新型催化剂提供了宝贵的指导。

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来源期刊

Applied Catalysis A: General 化学-环境科学

CiteScore

9.00

自引率

5.50%

发文量

415

审稿时长

24 days

期刊介绍： Applied Catalysis A: General publishes original papers on all aspects of catalysis of basic and practical interest to chemical scientists in both industrial and academic fields, with an emphasis onnew understanding of catalysts and catalytic reactions, new catalytic materials, new techniques, and new processes, especially those that have potential practical implications. Papers that report results of a thorough study or optimization of systems or processes that are well understood, widely studied, or minor variations of known ones are discouraged. Authors should include statements in a separate section "Justification for Publication" of how the manuscript fits the scope of the journal in the cover letter to the editors. Submissions without such justification will be rejected without review.