E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin, K. A. Lysenko, V. I. Minkin
{"title":"Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures","authors":"E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin, K. A. Lysenko, V. I. Minkin","doi":"10.1134/S1070328423601309","DOIUrl":null,"url":null,"abstract":"<p>The Сd(II) complexes with redox amphoteric 2,6-di-(<i>tert</i>-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L<sup>1</sup> and L<sup>2</sup> (adducts <b>I</b>, <b>II</b>, and <b>III</b>) are synthesized. The structures of coordinated complexes <b>I</b>, <b>II</b>, and <b>III</b> are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (<b>II</b>) and 1838310 (<b>III</b>)) and confirmed by the <sup>1</sup>Н, <sup>13</sup>С, and <sup>113</sup>Cd NMR spectroscopy (for complexes <b>I</b> and <b>III</b>) and IR spectroscopy data.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 3","pages":"171 - 178"},"PeriodicalIF":1.1000,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423601309","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The Сd(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L1 and L2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the 1Н, 13С, and 113Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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