E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin, K. A. Lysenko, V. I. Minkin
{"title":"Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures","authors":"E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin, K. A. Lysenko, V. I. Minkin","doi":"10.1134/S1070328423601309","DOIUrl":null,"url":null,"abstract":"<p>The Сd(II) complexes with redox amphoteric 2,6-di-(<i>tert</i>-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L<sup>1</sup> and L<sup>2</sup> (adducts <b>I</b>, <b>II</b>, and <b>III</b>) are synthesized. The structures of coordinated complexes <b>I</b>, <b>II</b>, and <b>III</b> are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (<b>II</b>) and 1838310 (<b>III</b>)) and confirmed by the <sup>1</sup>Н, <sup>13</sup>С, and <sup>113</sup>Cd NMR spectroscopy (for complexes <b>I</b> and <b>III</b>) and IR spectroscopy data.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423601309","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The Сd(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L1 and L2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the 1Н, 13С, and 113Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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