Photocatalysis toward Microplastics Conversion: A Critical Review

IF 11.3 1区 化学 Q1 CHEMISTRY, PHYSICAL ACS Catalysis Pub Date : 2024-05-20 DOI:10.1021/acscatal.4c01449
Ganghua Zhou, Hangmin Xu, Hao Song, Jianjian Yi, Xiaozhi Wang*, Zupeng Chen* and Xingwang Zhu*, 
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Abstract

Microplastics (MPs, particle size < 5 mm) have become increasingly ubiquitous on Earth due to the cleavage and degradation of the heavy use of plastics. MPs have recently been reported to be detected in human blood, alveoli, breast milk, embryos, and other organs, raising concerns about their environmental risks. Photocatalysis has been identified as a potential means for MPs conversion, which utilizes solar energy to stimulate a semiconductor photocatalyst. However, the study of photocatalytic conversion of MPs is still in the incubation period. This review overviews the current state-of-the-art technologies for MPs conversion. Then, the fundamental principles, challenges, analytical techniques, and evaluation indexes of photocatalytic MPs reforming are highlighted. We have systematically summarized the recent advances in the photocatalytic conversion of MPs and identified the key factors influencing photocatalytic performance. Finally, we propose some perspectives for developing efficient photocatalytic systems for reforming MPs. This review will provide a guideline for developing and applying photocatalytic technology for reforming MPs, which will significantly contribute to developing this emerging research field.

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光催化转化微塑料:评论
由于大量使用塑料造成的裂解和降解,微塑料(MPs,粒径为 5 毫米)在地球上越来越无处不在。据报道,最近在人体血液、肺泡、母乳、胚胎和其他器官中都检测到了微塑料,这引起了人们对其环境风险的关注。光催化被认为是一种潜在的 MPs 转化手段,它利用太阳能刺激半导体光催化剂。然而,光催化转化 MPs 的研究仍处于起步阶段。本综述概述了目前最先进的 MPs 转化技术。然后,重点介绍了光催化重整 MPs 的基本原理、挑战、分析技术和评价指标。我们系统总结了 MPs 光催化转化的最新进展,并确定了影响光催化性能的关键因素。最后,我们提出了开发用于重整 MPs 的高效光催化系统的一些展望。本综述将为开发和应用光催化技术转化 MPs 提供指导,这将极大地促进这一新兴研究领域的发展。
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来源期刊
ACS Catalysis
ACS Catalysis CHEMISTRY, PHYSICAL-
CiteScore
20.80
自引率
6.20%
发文量
1253
审稿时长
1.5 months
期刊介绍: ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.
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