A novel GO hoisted SnO2–BiOBr bifunctional catalyst for the remediation of organic dyes under illumination by visible light and electrocatalytic water splitting†
Manshu Dhillon, Abhishek Naskar, Neha Kaushal, Shekhar Bhansali, Avishek Saha and Aviru Kumar Basu
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引用次数: 0
Abstract
It is imperative to develop affordable multi-functional catalysts based on transition metals for various applications, such as dye degradation or the production of green energy. For the first time, we propose a simple chemical bath method to create a SnO2–BiOBr–rGO heterojunction with remarkable photocatalytic and electrocatalytic activities. After introducing graphene oxide (GO) into the SnO2–BiOBr nanocomposite, the charge separation, electron mobility, surface area, and electrochemical properties were significantly improved. The X-ray diffraction results show the successful integration of GO into the SnO2–BiOBr nanocomposite. Systematic material characterization by scanning and transmission electron microscopy showed that the photocatalysts are composed of uniformly distributed SnO2 nanoparticles (∼11 nm) on the regular nanosheets of BiOBr (∼94 nm) and rGO. The SnO2–BiOBr–rGO photocatalyst has outstanding photocatalytic activity when it comes to reducing a variety of organic dyes like rhodamine B (RhB) and methylene blue (MB). Within 90 minutes of visible light illumination, degradation of a maximum of 99% for MB and 99.8% for RhB was noted. The oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) performance was also tested for the ternary nanocomposite, and significantly lower overpotential values of 0.34 and −0.11 V (vs. RHE) at 10 mA cm−2 were observed for the OER and HER, respectively. Furthermore, the Tafel slope values are 34 and 39 mV dec−1 for the OER and HER, respectively. The catalytic degradation of dyes with visible light and efficient OER and HER performance offer this work a broad spectrum of potential applications.
期刊介绍:
Nanoscale is a high-impact international journal, publishing high-quality research across nanoscience and nanotechnology. Nanoscale publishes a full mix of research articles on experimental and theoretical work, including reviews, communications, and full papers.Highly interdisciplinary, this journal appeals to scientists, researchers and professionals interested in nanoscience and nanotechnology, quantum materials and quantum technology, including the areas of physics, chemistry, biology, medicine, materials, energy/environment, information technology, detection science, healthcare and drug discovery, and electronics.