Carboxylic Acids in the Synthesis of Chemicals for Addressing Flow Assurance Challenges in Offshore Petroleum Production

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-21 DOI:10.2174/0113852728305998240517074146
Ronald W. P. Ortiz, Tatiana S. L. Maravilha, Allan Belati, Felipe J. S. Bispo, Evelin A. Manoel, Vinicius O. Oliveira Gonçalves, Vinicius Kartnaller, João Cajaiba
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Abstract

Flow assurance encompasses the technical challenges of transporting hydrocarbon mixtures from the reservoir to the platform and refineries. Challenges in flow assurance include gas hydrate plugs, deposition of paraffin wax, asphaltenes, naphthenates, scale, and corrosion. Managing these deposits incurs high costs due to production interruptions and remediation operations like pigging, solvent injection, acid dissolutions, and thermal treatments. Therefore, prevention methods, such as the use of chemicals that inhibit deposit formation, are preferred. This review consolidates scientific works highlighting the role of carboxylic acids in the synthesis of chemicals for addressing flow assurance challenges as starting materials or final products for direct use. These organic compounds are already employed for the mild remediation of scale and naphthenate deposits and inhibiting gas hydrate, paraffin wax, asphaltene, scale deposits, and corrosion. Moreover, they play a crucial role in developing green flow assurance challenges inhibitors, given that some, like fatty acids, amino acids, and aromatic carboxylic acids, can be derived from natural sources. The presence of the carboxylic acid group in polymers and biopolymers is also essential for the effectiveness of these products as inhibitors. The literature further suggests that carboxylic acids will play a key role in the future development of simultaneous gas hydrate, corrosion, and scale inhibitors.
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羧酸在合成用于应对海上石油生产中流量保证挑战的化学品中的应用
流动性保证包括将碳氢化合物混合物从储层输送到平台和炼油厂所面临的技术挑战。流量保证方面的挑战包括天然气水合物堵塞、石蜡沉积、沥青质、环烷酸盐、水垢和腐蚀。管理这些沉积物的成本很高,因为需要中断生产并进行修复作业,如管道疏通、注入溶剂、酸溶解和热处理。因此,人们更倾向于采用预防方法,如使用能抑制沉积物形成的化学品。本综述汇集了一些科学著作,重点介绍了羧酸作为起始材料或直接使用的最终产品,在合成用于解决流动保证难题的化学品中的作用。这些有机化合物已被用于对水垢和环烷酸盐沉积物进行温和修复,以及抑制天然气水合物、石蜡、沥青质、水垢沉积物和腐蚀。此外,由于脂肪酸、氨基酸和芳香族羧酸等一些物质可以从天然来源提取,它们在开发绿色流动保证挑战抑制剂方面发挥着至关重要的作用。聚合物和生物聚合物中羧酸基的存在对于这些产品作为抑制剂的有效性也至关重要。文献进一步表明,羧酸将在未来同时开发天然气水合物、腐蚀和结垢抑制剂方面发挥关键作用。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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