Water adsorption kinetics on graphene controlled by surface modification of supporting substrates

Abstract

Sensing layers with an increased affinity for water molecules are essential for the development of highly sensitive humidity sensors. Graphene possesses superior electrical properties that make it suitable for the fabrication of low-noise miniaturized sensors. However, the enhancement of water affinity by introducing surface defects such as covalently attached hydrophilic groups reduces the electrical conductivity of graphene. In this study, we exploit the wetting transparency of graphene to increase its water affinity without introducing defects. Kinetic measurements using a Kelvin probe with a large-diameter tip showed that the rate constant of water adsorption was higher for graphene deposited on a hydrophilic substrate. These findings suggest that the wetting transparency of graphene can be exploited to reduce defect introduction into the graphene sensing layer, and has potential applications in sensor technologies.