Reduction in the Input of Microplastics into the Aquatic Environment via Wastewater Treatment Plants in Germany

Philipp Lau, Julia Stein, Luisa Reinhold, Matthias Barjenbruch, Tim Fuhrmann, Ingo Urban, Katrin Bauerfeld, Andrea Holte
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Abstract

Microplastic (MP) has emerged as a significant environmental challenge due to increased plastic production and its widespread presence in the environment. This study aimed to assess MP concentrations throughout the treatment process at nine wastewater treatment plants (WWTPs) in Germany, from influent to effluent. A customized sampling technique was employed, followed by field and laboratory preparation and the quantification of polymers (PE, PP, PS, PMMA, and PET) using TED-GCMS. MP concentrations decreased progressively in the WWTPs, with influent concentrations ranging from 2.5 to 13.6 mg/L. Effluent concentrations in the conventional WWTPs ranged from 0.001 to 0.051 mg/L, while advanced treatment via filtration yielded concentrations below the limit of quantification at 0.005 mg/L. All tested of the WWTPs demonstrated an over 99% removal efficiency for microplastics. Despite effective retention by the WWTPs, a critical evaluation of the results is necessary. There is a need to optimize existing technologies and enhance the standardization of sampling, processing, and measurement methods, as well as intensify efforts towards creating preventive measures to reduce plastic emissions.
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德国减少通过污水处理厂向水生环境排放微塑料
由于塑料产量的增加及其在环境中的广泛存在,微塑料 (MP) 已成为一项重大的环境挑战。本研究旨在评估德国九家污水处理厂(WWTP)从进水到出水整个处理过程中的微塑料浓度。采用了一种定制的采样技术,然后进行现场和实验室制备,并使用 TED-GCMS 对聚合物(聚乙烯、聚丙烯、聚苯乙烯、聚甲基丙烯酸甲酯和聚对苯二甲酸乙二酯)进行定量。污水处理厂中的 MP 浓度逐渐降低,进水浓度从 2.5 毫克/升到 13.6 毫克/升不等。传统污水处理厂的出水浓度为 0.001 至 0.051 毫克/升,而通过过滤进行高级处理后的浓度低于定量限,为 0.005 毫克/升。所有经过测试的污水处理厂对微塑料的去除率均超过 99%。尽管污水处理厂有效地保留了微塑料,但仍有必要对结果进行严格评估。有必要优化现有技术,加强取样、处理和测量方法的标准化,并加大力度制定减少塑料排放的预防措施。
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