Ultraefficient Ammonia Gas Sensors Based on Pt‐Loaded WO3 Nanobars

Montawat Wiboon, Pimpan Leangtanom, Kata Jaruwongrungsee, N. Chanlek, A. Wisitsoraat, V. Yordsri, Patcharee Kongpark, P. Pookmanee, V. Kruefu
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Abstract

Herein, unloaded WO3 (WO3) and Pt‐loaded WO3 (Pt‐WO3) nanobars are successfully synthesized through simple hydrothermal and impregnation methods. X‐ray diffractometer analysis confirms the formation of a monoclinic WO3 structure. Surface analysis reveals that the Pt impregnation results in a significant increase in the specific surface area of WO3 nanobars. The gas‐sensing performance of sensors based on nanobars is measured toward ammonia (NH3) with varying NH3 concentrations at different operating temperatures. Compared with the pristine WO3 sensor, the Pt‐WO3‐based sensor with an optimal Pt content of 1 wt% exhibits a relatively low optimum operating temperature of 250 °C and a superior response of 960–50 ppm NH3. Furthermore, the Pt‐WO3‐based sensor also displays fast response, excellent NH3 selectivity to ammonia, moderate humidity dependence, and good stability. Therefore, the developed hydrothermal and impregnation methods could be a suitable alternative procedure for the synthesis of Pt‐WO3 nanobars useful for advanced NH3‐sensing applications.
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基于铂负载 WO3 纳米棒的超高效氨气传感器
本文通过简单的水热法和浸渍法成功合成了无负载 WO3(WO3)和负载铂的 WO3(Pt-WO3)纳米棒。X 射线衍射仪分析证实了单斜 WO3 结构的形成。表面分析表明,铂浸渍使 WO3 纳米棒的比表面积显著增加。测量了基于纳米棒的传感器在不同工作温度下对不同浓度氨气(NH3)的气体传感性能。与原始 WO3 传感器相比,最佳铂含量为 1 wt% 的基于 Pt-WO3 的传感器的最佳工作温度相对较低,为 250 °C,对 960-50 ppm NH3 的响应较好。此外,这种基于 Pt-WO3 的传感器还具有响应速度快、对氨的 NH3 选择性优异、湿度依赖性适中以及稳定性好等特点。因此,所开发的水热法和浸渍法可能是合成适用于先进 NH3 传感应用的 Pt-WO3 纳米棒的合适替代方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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