Occurrence and mobility of shale oil in the Jiyang Depression, eastern China

IF 2.7 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Journal of Asian Earth Sciences Pub Date : 2024-05-28 DOI:10.1016/j.jseaes.2024.106187
Xiaojun Zhu , Shaolong Zhang , Jingong Cai , Huimin Liu , Zheng Li
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Abstract

The occurrence of shale oil is important for its mobility and holds great significance in determining the available shale oil resources. Here, shale samples from three representative wells with different shale oil production levels in the Jiyang Depression, eastern China, were collected to evaluate the mobility of shale oil from its occurrence. The samples were subjected to Rock-Eval pyrolysis, X-ray diffraction, soluble organic matter, and N2 adsorption measurements. The results indicate that the shales in the high production well have higher contents of clay or felsic minerals, more apolar oil components, and smaller pore sizes than those in the low production well. In particular, the shale oil occurrence exhibits two stages involving pore surface adsorption followed by pore void filling, which are separated by a total organic carbon (TOC) content of 0.6 wt% OC (equivalent to 7.7 mg/gRock, the lower threshold of shale oil content for mobility). The corresponding threshold of pore diameter is 10 nm. By integrating the shale oil occurrence with the oil properties at the producing intervals, the following indices are proposed to evaluate the shale oil mobility and high production level: shale oil content greater than 0.6 wt% OC or 7.7 mg/gRock, oil saturation index greater than 100 mg/gTOC, apolarity index greater than 1, and pore diameter greater than 10 nm. Our work provides an index regime to evaluate the mobility and high production probability of shale oil, which will benefit the exploration and development of shale oil resources.

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中国东部济阳坳陷页岩油的出现和流动性
页岩油的出现对其流动性非常重要,对确定页岩油的可利用资源具有重要意义。本文采集了中国东部济阳凹陷三口不同页岩油生产水平的代表性油井的页岩样品,以评估页岩油发生的流动性。对样品进行了Rock-Eval热解、X射线衍射、可溶性有机物和N2吸附测量。结果表明,与低产井的页岩相比,高产井的页岩具有更高的粘土或长石矿物含量、更多的极性油成分以及更小的孔隙尺寸。特别是,页岩油的出现表现出两个阶段,先是孔隙表面吸附,然后是孔隙空隙填充,这两个阶段以总有机碳(TOC)含量为 0.6 wt% OC(相当于 7.7 mg/gRock,这是页岩油含量的流动性下限)为分界线。相应的孔隙直径阈值为 10 纳米。通过综合页岩油出现情况和产区的石油性质,我们提出了以下指标来评价页岩油的流动性和高产水平:页岩油含量大于 0.6 wt% OC 或 7.7 mg/gRock,石油饱和度指数大于 100 mg/gTOC,极性指数大于 1,孔隙直径大于 10 nm。我们的研究为评估页岩油的流动性和高产概率提供了一个指标体系,这将有利于页岩油资源的勘探和开发。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Asian Earth Sciences
Journal of Asian Earth Sciences 地学-地球科学综合
CiteScore
5.90
自引率
10.00%
发文量
324
审稿时长
71 days
期刊介绍: Journal of Asian Earth Sciences has an open access mirror journal Journal of Asian Earth Sciences: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. The Journal of Asian Earth Sciences is an international interdisciplinary journal devoted to all aspects of research related to the solid Earth Sciences of Asia. The Journal publishes high quality, peer-reviewed scientific papers on the regional geology, tectonics, geochemistry and geophysics of Asia. It will be devoted primarily to research papers but short communications relating to new developments of broad interest, reviews and book reviews will also be included. Papers must have international appeal and should present work of more than local significance. The scope includes deep processes of the Asian continent and its adjacent oceans; seismology and earthquakes; orogeny, magmatism, metamorphism and volcanism; growth, deformation and destruction of the Asian crust; crust-mantle interaction; evolution of life (early life, biostratigraphy, biogeography and mass-extinction); fluids, fluxes and reservoirs of mineral and energy resources; surface processes (weathering, erosion, transport and deposition of sediments) and resulting geomorphology; and the response of the Earth to global climate change as viewed within the Asian continent and surrounding oceans.
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