{"title":"Supracolloidal step-growth polymerization of isotropic silica nanoparticles: a time-resolved small-angle X-ray scattering study","authors":"Tatsuki Oishi, Ayae Sugawara-Narutaki, Rintaro Takahashi","doi":"10.1038/s41428-024-00922-9","DOIUrl":null,"url":null,"abstract":"We have investigated the self-assembly kinetics of silica nanoparticles (SNPs) into the polymer-like structure by time-resolved small-angle X-ray scattering (SAXS). The analysis of the SAXS data with a kinetic model revealed that the SNPs undergo self-assembly in a process akin to the step-growth polymerization of bifunctional monomers. This study offers a facile strategy to construct polymer-like structures from isotropic spherical nanoparticles.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":null,"pages":null},"PeriodicalIF":2.3000,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Journal","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1038/s41428-024-00922-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
We have investigated the self-assembly kinetics of silica nanoparticles (SNPs) into the polymer-like structure by time-resolved small-angle X-ray scattering (SAXS). The analysis of the SAXS data with a kinetic model revealed that the SNPs undergo self-assembly in a process akin to the step-growth polymerization of bifunctional monomers. This study offers a facile strategy to construct polymer-like structures from isotropic spherical nanoparticles.
期刊介绍：
Polymer Journal promotes research from all aspects of polymer science from anywhere in the world and aims to provide an integrated platform for scientific communication that assists the advancement of polymer science and related fields. The journal publishes Original Articles, Notes, Short Communications and Reviews.
Subject areas and topics of particular interest within the journal''s scope include, but are not limited to, those listed below:
Polymer synthesis and reactions
Polymer structures
Physical properties of polymers
Polymer surface and interfaces
Functional polymers
Supramolecular polymers
Self-assembled materials
Biopolymers and bio-related polymer materials
Polymer engineering.
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