Poly[[{μ2-5-[(dimethylamino)(thioxo)methoxy]benzene-1,3-dicarboxylato-κ4O1,O1′:O3,O3′}(μ2-4,4′-dipyridylamine-κ2N4:N4′)cobalt(II)] dimethylformamide hemisolvate monohydrate]

IUCrData Pub Date : 2024-06-01 DOI:10.1107/S2414314624004899

Hui-Yu Qin , Bing-Guang Zhang , Qiao-Zhen Sun , M. Weil (Editor)

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Abstract

The crystal structure of the title compound shows a layered arrangement parallel to the bc plane where [CoO₄N₂] octahedra are linked by dmtb^2– and dpa ligands.

In the crystal structure of the title compound, {[Co(C₁₁H₉NSO₅)(C₁₀H₉N₃)]0.5C₃H₇NO·H₂O}_n or {[Co(dmtb)(dpa)]·0.5DMF·H₂O}_n (dmtb^2– = 5-[(dimethylamino)thioxomethoxy]-1,3-benzenedicarboxylate and dpa = 4,4′-dipyridylamine), an assembly of periodic [Co(C₁₁H₉NSO₅)(C₁₀H₉N₃)]_n layers extending parallel to the bc plane is present. Each layer is constituted by distorted [CoO₄N₂] octahedra, which are connected through the μ₂-coordination modes of both dmtb^2– and dpa ligands. Occupationally disordered water and dimethylformamide (DMF) solvent molecules are located in the voids of the network to which they are connected through hydrogen-bonding interactions.

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聚[[{μ2-5-[(二甲基氨基)(硫酮)甲氧基]苯-1,3-二羧酸根-κ4 O 1,O 1′:O 3,O 3′}(μ2-4,4′-dipyr

在标题化合物的晶体结构中，{[Co(C11H9NSO5)(C10H9N3)]0.5C3H7NO-H2O} n 或 {[Co(dmtb)(dpa)]-0.5DMF-H2O}n（dmtb2- = 5-[（二甲基氨基）硫氧甲氧基]-1,3-苯二甲酸酯，dpa = 4,4′-二吡啶基胺），出现了平行于 bc 平面延伸的周期性[Co(C11H9NSO5)(C10H9N3)] n 层组合。每一层都由扭曲的[CoO4N2]八面体构成，这些八面体通过 dmtb2- 和 dpa 配体的 μ 2 配位模式连接在一起。占据无序的水和二甲基甲酰胺（DMF）溶剂分子位于网络的空隙中，它们通过氢键相互作用与网络连接。

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