{"title":"One-pot synthesis of HKUST-1 monolith for CO2 adsorption","authors":"Motomu Sakai, Ayaka Ito, Takaya Matsumoto, Masahiko Matsukata","doi":"10.1093/chemle/upae109","DOIUrl":null,"url":null,"abstract":"\n Shape-forming technology is essential for the widespread utilization of metal-organic frameworks. We developed a one-pot synthesis method for HKUST-1 monolith. HKUST-1 monolith was successfully prepared by the hydrothermal treatment of a Cu monolith in an aqueous solution of 1,3,5-benzenetricarboxylic acid, ethanol, and nitric acid without the addition of a metal source. The prepared HKUST-1 monolith showed CO2 adsorption properties comparable to those of commercially available HKUST-1 powdery crystals.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upae109","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Shape-forming technology is essential for the widespread utilization of metal-organic frameworks. We developed a one-pot synthesis method for HKUST-1 monolith. HKUST-1 monolith was successfully prepared by the hydrothermal treatment of a Cu monolith in an aqueous solution of 1,3,5-benzenetricarboxylic acid, ethanol, and nitric acid without the addition of a metal source. The prepared HKUST-1 monolith showed CO2 adsorption properties comparable to those of commercially available HKUST-1 powdery crystals.