Zhen-Zhen Xie, Yu Zheng, Zi-Hao Liao, Chu-Ping Yuan, Ming-Zhi Li, Ke-yi Deng, Haoyue Xiang, Kai Chen, Hua Yang
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引用次数: 0
Abstract
Herein, a practical, mild and convenient strategy was disclosed for the hydrogenation of alkenes under photocatalytic conditions through HAT/protonation process. A combination of experimental and computational studies suggested water was activated by a phosphine radical cation to generate the critical intermediate PR3(OH) radical, which acted as a “free” hydrogen atom to faciliate the initial HAT process.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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