Carbonation and corrosion of steel in fly ash concrete, concluding investigation of five-year-old laboratory specimens and preliminary field data

Abstract

Carbonation development and reinforcement corrosion were investigated on concretes exposed for a five-year period at 90% RH, 20 ℃, and 5% CO₂, and for a six-year period at natural carbonation. Portland cement-based binders with 0%, 18%, and 30% fly ash were investigated. The fly ash blends showed lower carbonation resistance compared to PC both at laboratory and field exposure, a large difference in carbonation performance was observed between the laboratory exposed specimens. The carbonation rate was fastest on the laboratory specimens and showed square-root time dependency the first 2.5 years, but reduced rate at later age. Deeper carbonation depths were in general observed in the vicinity of the reinforcement compared to the unreinforced laboratory exposed specimens. Not all specimens were fully carbonated at the steel-concrete interface. The correlation between degree of carbonation of the steel-mortar interface, the open circuit potential, and the observed corrosion of the steel bars varied between binders and bar position (top or bottom). The measured corrosion rate in the laboratory exposed (90% RH, 20 ℃, and 5% CO₂) carbonated concrete was on average 0.2 μA/cm², with an upper value of 0.6 μA/cm². The highest corrosion rate was measured in the fly ash concrete. No corrosion rate data are yet available for the field exposed concretes.