Jing Huang , Dawei Yi , Jingbo Yan , Bin Han , Yihang He , Zhen Yang , Yongli Zhou , Fang Yang
{"title":"Effects of Mn addition on oxidation behaviour of heat-resistant steel in a high-temperature steam environment","authors":"Jing Huang , Dawei Yi , Jingbo Yan , Bin Han , Yihang He , Zhen Yang , Yongli Zhou , Fang Yang","doi":"10.1016/j.corcom.2023.09.003","DOIUrl":null,"url":null,"abstract":"<div><p>A comparative study of high chromium (Super304H) and high manganese low chromium heat-resistant steel (HT630) was carried out at 650 °C in steam. Results indicate that the high manganese content in HT630 significantly improved its oxidation resistance. It is ascribed to the formation of a dense protective MnCr<sub>2</sub>O<sub>4</sub> oxide layer during oxidation. MnCr<sub>2</sub>O<sub>4</sub> layer effectively inhibits the diffusion of iron, suppresses the growth of iron-rich oxides, promotes the formation of an iron-rich protective interface with the matrix, and improves the overall oxidation resistance.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"14 ","pages":"Pages 72-84"},"PeriodicalIF":0.0000,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266924000239/pdfft?md5=81ef0128df487f46f42d3255a4bf0699&pid=1-s2.0-S2667266924000239-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Communications","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667266924000239","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A comparative study of high chromium (Super304H) and high manganese low chromium heat-resistant steel (HT630) was carried out at 650 °C in steam. Results indicate that the high manganese content in HT630 significantly improved its oxidation resistance. It is ascribed to the formation of a dense protective MnCr2O4 oxide layer during oxidation. MnCr2O4 layer effectively inhibits the diffusion of iron, suppresses the growth of iron-rich oxides, promotes the formation of an iron-rich protective interface with the matrix, and improves the overall oxidation resistance.