Zilian Qi, Haojie Li, Kun Cao, Eryan Gu, Yanwei Wen, Junzhou Long, Bin Shan, Rong Chen
{"title":"Area Selective Deposition of Ru on W/SiO2 Nanopatterns via Sequential Reactant Dosing and Thermal Defect Correction","authors":"Zilian Qi, Haojie Li, Kun Cao, Eryan Gu, Yanwei Wen, Junzhou Long, Bin Shan, Rong Chen","doi":"10.1021/acs.chemmater.4c00475","DOIUrl":null,"url":null,"abstract":"Area selective deposition (ASD) of ruthenium offers a promising approach to fabricate ultrathin, continuous, and low-resistivity films for metallic interconnection in various microelectronic applications. This study employs an advanced sequential reactant dosing combined with a thermal defect correction strategy to obtain high selectivity and film quality. Through the adoption of sequential reactant dosing, chemisorption becomes the prevailing mechanism and effectively prevents excess physical adsorption. This method not only enhances coverage but also reduces steric hindrance from occupying the neighboring active sites, aligning with Kinetic Monte Carlo simulations. The defect correction process benefits from a low temperature and inert atmosphere, which curtails nanoparticle coarsening due to Ostwald ripening. Additionally, reducing particle size via sequential dosing facilitates defect migration and increases selectivity. The robust ASD technique is successfully applied to W/SiO<sub>2</sub> nanopatterns for metal interconnects, achieving ∼5 nm Ru on tungsten while no detectable defects on SiO<sub>2</sub> areas, which offers an encouraging method for advanced semiconductor nodes.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":7.2000,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acs.chemmater.4c00475","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Area selective deposition (ASD) of ruthenium offers a promising approach to fabricate ultrathin, continuous, and low-resistivity films for metallic interconnection in various microelectronic applications. This study employs an advanced sequential reactant dosing combined with a thermal defect correction strategy to obtain high selectivity and film quality. Through the adoption of sequential reactant dosing, chemisorption becomes the prevailing mechanism and effectively prevents excess physical adsorption. This method not only enhances coverage but also reduces steric hindrance from occupying the neighboring active sites, aligning with Kinetic Monte Carlo simulations. The defect correction process benefits from a low temperature and inert atmosphere, which curtails nanoparticle coarsening due to Ostwald ripening. Additionally, reducing particle size via sequential dosing facilitates defect migration and increases selectivity. The robust ASD technique is successfully applied to W/SiO2 nanopatterns for metal interconnects, achieving ∼5 nm Ru on tungsten while no detectable defects on SiO2 areas, which offers an encouraging method for advanced semiconductor nodes.
期刊介绍:
The journal Chemistry of Materials focuses on publishing original research at the intersection of materials science and chemistry. The studies published in the journal involve chemistry as a prominent component and explore topics such as the design, synthesis, characterization, processing, understanding, and application of functional or potentially functional materials. The journal covers various areas of interest, including inorganic and organic solid-state chemistry, nanomaterials, biomaterials, thin films and polymers, and composite/hybrid materials. The journal particularly seeks papers that highlight the creation or development of innovative materials with novel optical, electrical, magnetic, catalytic, or mechanical properties. It is essential that manuscripts on these topics have a primary focus on the chemistry of materials and represent a significant advancement compared to prior research. Before external reviews are sought, submitted manuscripts undergo a review process by a minimum of two editors to ensure their appropriateness for the journal and the presence of sufficient evidence of a significant advance that will be of broad interest to the materials chemistry community.