Development of an efficient renewable corrosion-inhibiting agent from Acacia auriculiformis seed oil

IF 1.8 4区 材料科学 Q4 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY Green Materials Pub Date : 2024-06-15 DOI:10.1680/jgrma.24.00009
Anirban Chakraborty, Sharmistha Dhar, Mahua Ghosh, Debarati Mitra
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Abstract

Corrosion is a cost-worthy problem all over the world. Current approaches to control corrosion have some paucity of efficiency which triggers the search for novel materials that are green, cheap, and made from renewable resources. In this study, an attempt was made to prepare Acacia auriculiformis seed oil (ASO) based fatty amide (AFAM) through a simple reaction route involving aminolysis of ASO fatty acid (AFA) and diethylenetriamine (DETA). FTIR and 1HNMR were used to determine the structural characterisation of the synthesised amide. Properties like acid value, amine value, refractive index, and specific gravity were measured. The coating films were prepared by using a standard formulation, in which synthesised fatty amide was added in different proportions. The performance of the cured films was evaluated and compared. The hydrophobicity test reveals that the hydrophobicity of film increases with the addition of fatty amide up to 2% then decreases. The effect of the synthesised product on mild steel was investigated as per the standard protocol. The results revealed that developed fatty amide inhibits the corrosion of carbon steel up to a certain concentration (2%) in the film.
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从金合欢种子油中开发高效的可再生缓蚀剂
在世界各地,腐蚀都是一个代价高昂的问题。目前控制腐蚀的方法效率不高,因此人们开始寻找绿色、廉价且由可再生资源制成的新型材料。本研究尝试通过简单的反应路线制备以金合欢种子油(ASO)为基础的脂肪酰胺(AFAM),其中包括 ASO 脂肪酸(AFA)和二乙烯三胺(DETA)的氨解反应。傅立叶变换红外光谱和 1HNMR 被用来确定合成酰胺的结构特征。还测量了酸值、胺值、折射率和比重等特性。使用标准配方制备涂膜,其中按不同比例添加合成脂肪酰胺。对固化薄膜的性能进行了评估和比较。疏水性测试表明,薄膜的疏水性随着脂肪酰胺添加量的增加而增加,最高达 2%,然后降低。按照标准方案研究了合成产品对低碳钢的影响。结果表明,在薄膜中添加一定浓度(2%)的脂肪酰胺可抑制碳钢的腐蚀。
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来源期刊
Green Materials
Green Materials Environmental Science-Pollution
CiteScore
3.50
自引率
15.80%
发文量
24
期刊介绍: The focus of Green Materials relates to polymers and materials, with an emphasis on reducing the use of hazardous substances in the design, manufacture and application of products.
期刊最新文献
Facile synthesis of bimetallic metal-organic frameworks for highly efficient UV shielding Development of an efficient renewable corrosion-inhibiting agent from Acacia auriculiformis seed oil Preparation of clay inhibitor based on pomegranate peel extract and its application in drilling fluids Facile armour production from cocoon waste by a cold pressing process Developing of nanocellulose loaded chitosan-polylactic acid biofilms for green food packaging
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