{"title":"Development of an efficient renewable corrosion-inhibiting agent from Acacia auriculiformis seed oil","authors":"Anirban Chakraborty, Sharmistha Dhar, Mahua Ghosh, Debarati Mitra","doi":"10.1680/jgrma.24.00009","DOIUrl":null,"url":null,"abstract":"Corrosion is a cost-worthy problem all over the world. Current approaches to control corrosion have some paucity of efficiency which triggers the search for novel materials that are green, cheap, and made from renewable resources. In this study, an attempt was made to prepare Acacia auriculiformis seed oil (ASO) based fatty amide (AFAM) through a simple reaction route involving aminolysis of ASO fatty acid (AFA) and diethylenetriamine (DETA). FTIR and 1HNMR were used to determine the structural characterisation of the synthesised amide. Properties like acid value, amine value, refractive index, and specific gravity were measured. The coating films were prepared by using a standard formulation, in which synthesised fatty amide was added in different proportions. The performance of the cured films was evaluated and compared. The hydrophobicity test reveals that the hydrophobicity of film increases with the addition of fatty amide up to 2% then decreases. The effect of the synthesised product on mild steel was investigated as per the standard protocol. The results revealed that developed fatty amide inhibits the corrosion of carbon steel up to a certain concentration (2%) in the film.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"8 46","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1680/jgrma.24.00009","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Corrosion is a cost-worthy problem all over the world. Current approaches to control corrosion have some paucity of efficiency which triggers the search for novel materials that are green, cheap, and made from renewable resources. In this study, an attempt was made to prepare Acacia auriculiformis seed oil (ASO) based fatty amide (AFAM) through a simple reaction route involving aminolysis of ASO fatty acid (AFA) and diethylenetriamine (DETA). FTIR and 1HNMR were used to determine the structural characterisation of the synthesised amide. Properties like acid value, amine value, refractive index, and specific gravity were measured. The coating films were prepared by using a standard formulation, in which synthesised fatty amide was added in different proportions. The performance of the cured films was evaluated and compared. The hydrophobicity test reveals that the hydrophobicity of film increases with the addition of fatty amide up to 2% then decreases. The effect of the synthesised product on mild steel was investigated as per the standard protocol. The results revealed that developed fatty amide inhibits the corrosion of carbon steel up to a certain concentration (2%) in the film.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.