Intriguing Brownian diffusivity characteristics of complex nano-particles

Sukalyan Bhattacharya, Paula Cano-Fossi
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Abstract

This article reveals how apparently similar looking nano-particles with same size, shape and mass may exhibit widely varying Brownian diffusivity due to inherent features of nano-scale dynamics. Such variabilities may, in certain cases, reach order of magnitude fluctuations depending on the interfacial and bulk properties of the Brownian body. Accordingly, the theory explains several unanswered questions in connection to submicron systems including anomalous thermal properties of nano-fluids and strangely varying transmittivities of biologically originated particulate droplets.
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复杂纳米颗粒的迷人布朗扩散特性
这篇文章揭示了具有相同大小、形状和质量的看似相似的纳米颗粒,是如何由于纳米尺度动力学的固有特征而表现出千差万别的布朗扩散性的。在某些情况下,这种变化可能达到数量级的波动,这取决于布朗体的界面和块体特性。因此,该理论可以解释与亚微米系统有关的几个未解之谜,包括纳米流体的异常热特性和生物微粒液滴的奇异透射率变化。
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