{"title":"A novel Schiff base-containing phthalocyanine and its azo dye-substituted analogue: the effect of pH on colour","authors":"Günay Kaya Kantar","doi":"10.1071/ch24014","DOIUrl":null,"url":null,"abstract":"There are many studies in the literature devoted to the synthesis of phthalocyanines substituted with Schiff bases and azo dyes and their particular properties. However, the comparison of spectral properties of these analogue compounds has not been investigated up to now. Therefore, a new eugenol group-bearing Schiff base-substituted zinc(II) phthalocyanine compound was synthesised and characterised and its UV/Vis spectral properties were compared with its azo dye analogue at different pH. It was determined that the azo dye analogue showed more pronounced spectral changes than the Schiff base-substituted phthalocyanine, depending on pH.","PeriodicalId":8575,"journal":{"name":"Australian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Australian Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1071/ch24014","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
There are many studies in the literature devoted to the synthesis of phthalocyanines substituted with Schiff bases and azo dyes and their particular properties. However, the comparison of spectral properties of these analogue compounds has not been investigated up to now. Therefore, a new eugenol group-bearing Schiff base-substituted zinc(II) phthalocyanine compound was synthesised and characterised and its UV/Vis spectral properties were compared with its azo dye analogue at different pH. It was determined that the azo dye analogue showed more pronounced spectral changes than the Schiff base-substituted phthalocyanine, depending on pH.
期刊介绍：
Australian Journal of Chemistry - an International Journal for Chemical Science publishes research papers from all fields of chemical science. Papers that are multidisciplinary or address new or emerging areas of chemistry are particularly encouraged. Thus, the scope is dynamic. It includes (but is not limited to) synthesis, structure, new materials, macromolecules and polymers, supramolecular chemistry, analytical and environmental chemistry, natural products, biological and medicinal chemistry, nanotechnology, and surface chemistry.
Australian Journal of Chemistry is published with the endorsement of the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and the Australian Academy of Science.
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