Light management of solar cells by implementation of nano/microstructures

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-12 DOI:10.1142/s0217984924420193
Xiyue Zhang, Bitao Chen, Zherui Wang, Jian He, Xinghua Zhan, Fei Chen, Fei Long
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Abstract

Research on the improvement of the photoelectric conversion efficiency of solar cells is always the focus. In this paper, an efficient anti-reflection micro/nanostructure is proposed to improve the conversion efficiency of the solar cell. Graded effective refractive index theory is used to achieve the anti-reflection effect while the simulation model is established by FDTD. A specific periodic nanostructure is obtained, which can achieve a good anti-reflection effect. According to the simulation model, the reflectivity of the solar cell is reduced by 0.85% and the transmittance is increased by 0.85% in the band range of 200 nm to 1000 nm. Specifically, high anti-reflection phenomena are obtained in the band range of ultraviolet and blue light, in which the reflectivity is reduced by 1.56% and the transmittance is increased by 1.55%. Based on the simulation results, the array nanostructure is produced by etching the self-assembled polystyrene (PS) microspheres. Finally, the required structure is formed on the silicon wafer by nanoimprinting and etching technology. The reflectivity of 2.8% is obtained on silicon, which can potentially increase the opto-electrical performance of the solar cell.
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通过实施纳米/微结构实现太阳能电池的光管理
提高太阳能电池的光电转换效率一直是研究的重点。本文提出了一种高效的抗反射微/纳米结构,以提高太阳能电池的转换效率。本文采用梯度有效折射率理论来实现抗反射效果,并通过 FDTD 建立了仿真模型。得到了一种特定的周期性纳米结构,它能达到良好的抗反射效果。根据仿真模型,在 200 纳米到 1000 纳米的波段范围内,太阳能电池的反射率降低了 0.85%,透射率提高了 0.85%。特别是在紫外线和蓝光的波段范围内,获得了高抗反射现象,其中反射率降低了 1.56%,透射率提高了 1.55%。根据模拟结果,通过蚀刻自组装聚苯乙烯(PS)微球,制作出阵列纳米结构。最后,通过纳米压印和蚀刻技术在硅晶片上形成所需的结构。硅片上的反射率为 2.8%,这有可能提高太阳能电池的光电性能。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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