Coupling Effect of Precipitates and Hydrogen on Pitting Corrosion of Stainless Steel

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-12 DOI:10.5006/4549
Ming Liu, Guanghu Yao, Xuehan Wang, Lining Xu, Lang Jiao, Hang Su, Anqing Fu
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Abstract

This study investigated the coupling effect of hydrogen and precipitates on the initiation of pitting using HR3C stainless steel with large NbCrN precipitates as the study material. Stainless steel exhibited good resistance to pitting when not subject to hydrogen charging. Hydrogen charging significantly reduced the corrosion resistance and stability of the passive film. Results obtained using the hydrogen microprint technique revealed that hydrogen was enriched within NbCrN precipitates and along the precipitate–substrate interface. Through immersion experiments, we discovered that pits preferentially initiated at the precipitate–substrate interface because it had weaker corrosion resistance than the precipitates.
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析出物和氢对不锈钢点腐蚀的耦合效应
本研究以含有大量铌铬镍析出物的 HR3C 不锈钢为研究材料,探讨了氢和析出物对点蚀引发的耦合效应。不锈钢在未充氢时表现出良好的抗点蚀性。充氢明显降低了被动膜的耐腐蚀性和稳定性。使用氢显微印迹技术获得的结果显示,氢在 NbCrN 沉淀内部以及沿沉淀-基底界面富集。通过浸泡实验,我们发现,由于析出物-基底界面的耐腐蚀性弱于析出物,因此凹坑更倾向于在析出物-基底界面处形成。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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