1,4-Diazabicyclo[2.2.2]octane (DABCO) in Organic Synthesis and Catalysis: A Quinquennial Report (2019-to date)

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-12 DOI:10.2174/0113852728313865240528073519
Ravi Varala, Vittal Seema, Mohammed Mujahid Alam, Mohammed Amanullah, Beda Durga Prasad
{"title":"1,4-Diazabicyclo[2.2.2]octane (DABCO) in Organic Synthesis and Catalysis: A\nQuinquennial Report (2019-to date)","authors":"Ravi Varala, Vittal Seema, Mohammed Mujahid Alam, Mohammed Amanullah, Beda Durga Prasad","doi":"10.2174/0113852728313865240528073519","DOIUrl":null,"url":null,"abstract":"\n\nDABCO is one of the more effective basic organocatalysts/reagents that can be used for a range of\norganic transformations, including C-H functionalization, formation of hetero-hetero bonds, rearrangements, the\nsynthesis of heterocyclic compounds, cyclizations and annulations, other miscellaneous reactions. This\nquinquennial review aims to critically and perceptively address noteworthy contributions of non chiral catalyst\nDABCO for regular organic transformations from 2019 onward. The key areas of attention were the advantages\nand limits of the approach, in addition to the mechanistic pathway, which is required for a specific organic\ntransformation to be performed effectively.\n","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"28 8","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.2174/0113852728313865240528073519","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

DABCO is one of the more effective basic organocatalysts/reagents that can be used for a range of organic transformations, including C-H functionalization, formation of hetero-hetero bonds, rearrangements, the synthesis of heterocyclic compounds, cyclizations and annulations, other miscellaneous reactions. This quinquennial review aims to critically and perceptively address noteworthy contributions of non chiral catalyst DABCO for regular organic transformations from 2019 onward. The key areas of attention were the advantages and limits of the approach, in addition to the mechanistic pathway, which is required for a specific organic transformation to be performed effectively.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
有机合成和催化中的 1,4-二氮杂双环[2.2.2]辛烷 (DABCO):五年期报告(2019 年至今)
DABCO 是较为有效的基本有机催化剂/试剂之一,可用于一系列有机转化,包括 C-H 功能化、杂-杂键的形成、重排、杂环化合物的合成、环化和环化以及其他杂项反应。这篇五年一度的综述旨在批判性地、敏锐地探讨非手性催化剂DABCO自2019年以来在常规有机转化中做出的值得注意的贡献。重点关注的领域包括该方法的优势和局限,以及有效进行特定有机转化所需的机理途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
期刊最新文献
Corrigendum to "Do All Isolated Traumatic Subarachnoid Hemorrhages Need to Be Transferred to a Level 1 Trauma Center?" Proton-Coupled Electron and Energy Transfer in Molecular Triads. Chromenylium and Flavylium Polymethine Fluorophores Light Up the Shortwave Infrared Region Construction and Application of Nucleic Acids-Based Biomolecular Condensates Chemical Editing of Proteins: From a Specific Residue to Functional Domains.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1