Ravi Varala, Vittal Seema, Mohammed Mujahid Alam, Mohammed Amanullah, Beda Durga Prasad
{"title":"1,4-Diazabicyclo[2.2.2]octane (DABCO) in Organic Synthesis and Catalysis: A\nQuinquennial Report (2019-to date)","authors":"Ravi Varala, Vittal Seema, Mohammed Mujahid Alam, Mohammed Amanullah, Beda Durga Prasad","doi":"10.2174/0113852728313865240528073519","DOIUrl":null,"url":null,"abstract":"\n\nDABCO is one of the more effective basic organocatalysts/reagents that can be used for a range of\norganic transformations, including C-H functionalization, formation of hetero-hetero bonds, rearrangements, the\nsynthesis of heterocyclic compounds, cyclizations and annulations, other miscellaneous reactions. This\nquinquennial review aims to critically and perceptively address noteworthy contributions of non chiral catalyst\nDABCO for regular organic transformations from 2019 onward. The key areas of attention were the advantages\nand limits of the approach, in addition to the mechanistic pathway, which is required for a specific organic\ntransformation to be performed effectively.\n","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"28 8","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.2174/0113852728313865240528073519","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
DABCO is one of the more effective basic organocatalysts/reagents that can be used for a range of
organic transformations, including C-H functionalization, formation of hetero-hetero bonds, rearrangements, the
synthesis of heterocyclic compounds, cyclizations and annulations, other miscellaneous reactions. This
quinquennial review aims to critically and perceptively address noteworthy contributions of non chiral catalyst
DABCO for regular organic transformations from 2019 onward. The key areas of attention were the advantages
and limits of the approach, in addition to the mechanistic pathway, which is required for a specific organic
transformation to be performed effectively.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.