Enhanced simulated sunlight photocatalytic performance in K2Ti6O13/g-C3N4 heterojunction

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-12 DOI:10.1142/s0217984924504104
Zhi Li, Yuhan Jing, Qianxu Ye, Jie Wang, Nan Sun, Liexing Zhou, Jinming Cai
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Abstract

In this study, K2Ti6O[Formula: see text] (KTO) nanowires were doped with carbon (CKTO) via a novel solid-phase approach at 800∘C for the first time using ethanol, KF, and TiO2. In addition to the lower sintering temperature, a shorter insulation period was achieved compared to the conventional solid-phase method. Furthermore, by combining and calcining CKTO and g-C3N4, a CKTO/g-C3N4 heterojunction composite was produced. The rate at which CKTO/g-C3N4 photocatalytically degraded methylene blue was higher than those of pure CKTO and g-C3N4. Our study indicates that adding g-C3N4 enhances photocatalytic performance by reducing the recombination rate of photogenerated electron–hole pairs and narrowing the bandgap of the CKTO/g-C3N4 heterostructure. This paper presents a novel method for creating KTO composites in an eco-friendly and productive manner for the photocatalytic degradation of organic colors.
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增强 K2Ti6O13/g-C3N4 异质结的模拟太阳光光催化性能
在这项研究中,首次使用乙醇、KF 和 TiO2 在 800∘C 温度下通过新型固相方法在 K2Ti6O [式:见正文] (KTO)纳米线中掺杂了碳(CKTO)。与传统的固相方法相比,该方法不仅烧结温度更低,而且绝缘时间更短。此外,通过将 CKTO 和 g-C3N4 结合并煅烧,制备出了 CKTO/g-C3N4 异质结复合材料。与纯 CKTO 和 g-C3N4 相比,CKTO/g-C3N4 光催化降解亚甲基蓝的速率更高。我们的研究表明,添加 g-C3N4 可降低光生电子-空穴对的重组率,缩小 CKTO/g-C3N4 异质结构的带隙,从而提高光催化性能。本文提出了一种新型方法,以环保和高效的方式制造 KTO 复合材料,用于有机色素的光催化降解。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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