Electrical Conductivity of Subsurface Ocean Analogue Solutions from Molecular Dynamics Simulations

IF 2.9 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ACS Earth and Space Chemistry Pub Date : 2024-06-08 DOI:10.1021/acsearthspacechem.3c00345
Catherine A. Psarakis*, Timothy Tizhe Fidelis, Keith B. Chin, Baptiste Journaux, Abby Kavner, Pranab Sarker, Marshall J. Styczinski, Steven D. Vance and Tao Wei, 
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Abstract

Investigating the habitability of ocean worlds is a priority of current and future NASA missions. The Europa Clipper mission will conduct approximately 50 flybys of Jupiter’s moon Europa, returning a detailed portrait of its interior from the synthesis of data from its instrument suite. The magnetometer on board has the capability of decoupling Europa’s induced magnetic field to high precision, and when these data are inverted, the electrical conductivity profile from the electrically conducting subsurface salty ocean may be constrained. To optimize the interpretation of magnetic induction data near ocean worlds and constrain salinity from electrical conductivity, accurate laboratory electrical conductivity data are needed under the conditions expected in their subsurface oceans. At the high-pressure, low-temperature (HPLT) conditions of icy worlds, comprehensive conductivity data sets are sparse or absent from either laboratory data or simulations. We conducted molecular dynamics simulations of candidate ocean compositions of aqueous NaCl under HPLT conditions at multiple concentrations. Our results predict electrical conductivity as a function of temperature, pressure, and composition, showing a decrease in conductivity as the pressure increases deeper into the interior of an icy moon. These data can guide laboratory experiments at conditions relevant to icy moons and can be used in tandem to forward-model the magnetic induction signals at ocean worlds and compare with future spacecraft data. We discuss implications for the Europa Clipper mission.

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从分子动力学模拟看地下海洋模拟溶液的电导率
调查海洋世界的宜居性是美国国家航空航天局当前和未来任务的优先事项。木卫二快船号任务将对木星的卫星木卫二进行约 50 次飞越,通过综合其仪器套件的数据,传回木卫二内部的详细情况。搭载的磁力计能够高精度地解耦木卫二的感应磁场,当这些数据被反演时,导电的地表下咸海的电导率曲线可能会得到约束。为了优化对海洋世界附近磁感应数据的解释,并通过电导率来确定盐度,需要在海洋世界表层下海洋的预期条件下获得精确的实验室电导率数据。在冰雪世界的高压、低温(HPLT)条件下,无论是实验室数据还是模拟数据都很少或没有全面的电导率数据集。我们对 HPLT 条件下多种浓度的氯化钠水溶液的候选海洋成分进行了分子动力学模拟。我们的结果预测了电导率与温度、压力和成分的函数关系,显示出随着压力的增加,冰月内部的电导率会降低。这些数据可以指导冰卫星相关条件下的实验室实验,并可用于对海洋世界的磁感应信号进行正向建模,以及与未来的航天器数据进行比较。我们讨论了对欧罗巴号快船任务的影响。
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来源期刊
ACS Earth and Space Chemistry
ACS Earth and Space Chemistry Earth and Planetary Sciences-Geochemistry and Petrology
CiteScore
5.30
自引率
11.80%
发文量
249
期刊介绍: The scope of ACS Earth and Space Chemistry includes the application of analytical, experimental and theoretical chemistry to investigate research questions relevant to the Earth and Space. The journal encompasses the highly interdisciplinary nature of research in this area, while emphasizing chemistry and chemical research tools as the unifying theme. The journal publishes broadly in the domains of high- and low-temperature geochemistry, atmospheric chemistry, marine chemistry, planetary chemistry, astrochemistry, and analytical geochemistry. ACS Earth and Space Chemistry publishes Articles, Letters, Reviews, and Features to provide flexible formats to readily communicate all aspects of research in these fields.
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