Structure and properties of alumina-reinforced copper matrix composites prepared by powder metallurgy at different sintering temperatures

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-06 DOI:10.1142/s0217984924420181
Baisong Hu, Jiheng Wang, Hu Zhou, Hengyi Liu
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Abstract

In this paper, alumina-reinforced copper-based composite materials were prepared by using the electroless plating method to coat copper powder with a layer of silver and then combining the solution sol method and powder metallurgy method. The results show that recrystallized structures and twins appear in composite materials after high-temperature sintering. As the sintering temperature increases, the ratio of recrystallized structures and twins gradually decreases, and straight coherent [Formula: see text]3 annealing twins appear in the structure, the number of high-angle grain boundaries decreased, the number of small-angle grain boundaries continues to increase, the average grain size increased from 3.89 to 4.83[Formula: see text][Formula: see text]m, the tensile strength increased from 156[Formula: see text]MPa to 167.5[Formula: see text]MPa, the maximum elongation was 9.4%, and the density increased from 6.81[Formula: see text]g/cm3 increased to 7.62[Formula: see text]g/cm3, the porosity dropped from 13.3% to 5.5%, the conductivity increased from 60.3% IACS to 73.2% IACS, the maximum hardness value was 68.71 HV, the best performance of the composite was achieved by sintering at 900°C with the tensile strength and elongation are 163[Formula: see text]MPa and 9%, respectively, the conductivity is 68.9% IACS, and the density is 7.35[Formula: see text]g/cm3. Its fracture surface shows mostly ductile features.
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不同烧结温度下粉末冶金制备的氧化铝增强铜基复合材料的结构与性能
本文采用化学电镀法在铜粉表面镀一层银,然后结合溶胶法和粉末冶金法制备了氧化铝增强铜基复合材料。结果表明,高温烧结后复合材料出现再结晶结构和孪晶。随着烧结温度的升高,再结晶结构和孪晶的比例逐渐减小,结构中出现了直相贯[式:见正文]3退火孪晶,高角度晶界数量减少,小角度晶界数量继续增加,平均晶粒尺寸从 3.89 增加到 4.83[式:见正文]。89增至4.83[式中:见正文][式中:见正文]m,抗拉强度由156[式中:见正文]MPa增至167.5[式中:见正文]MPa,最大伸长率为9.4%,密度从 6.81[式中:见正文]g/cm3增至 7.62[式中:见正文]g/cm3,孔隙率从 13.3%降至 5.5%,导电率从 60.3% IACS增至 73.2% IACS,最大硬度值为 68.在 900°C 下烧结的复合材料性能最佳,拉伸强度和伸长率分别为 163[计算公式见正文]MPa 和 9%,电导率为 68.9% IACS,密度为 7.35[计算公式见正文]g/cm3。其断裂面主要呈现韧性特征。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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