Preparation, Synthesis and Characterization of La(1-x)Sr(x)MnO3 Alloy

Ramlan Ramlan, Fatma Husaini, Jan Setiawan, Ferry Budhi Susetyo, H. Notonegoro, Silviana Simbolon, D. Nanto, Y. Yunasfi
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Abstract

Magnetic particles have been used for hyperthermia by inserting ferromagnetic material into tumor tissue. La(1-x)Sr(x)MnO3 is one of the best candidates for hyperthermia due to higher magnetic at ambient temperature and their Curie temperature easily adjusted. This research synthesized La(1-x)Sr(x)MnO3 using the ball milling technique. Several heat treatments were also conducted after ball milling processing. Various investigations, including SEM-EDS, XRD, DSC, and VSM, were conducted. LaMnO3 has a hexagonal structure, which has the space group R -3 c. From the diffraction pattern seen in LaMnO3 and La0.9Sr0.1MnO3 seen at angles 32.376 and 32.706, it looks separate like the database diffraction pattern. In La0.9Sr0.1MnO3, these two peaks are seen to be increasingly separated. In contrast to the diffraction patterns of La0.7Sr0.3MnO3 and La0.5Sr0.5MnO3 at an angle of 32.376, there is a decrease in intensity. The specific heat capacity of the alloy with Sr substitution of 0.3 has a greater value than that without substitution and the lowest occurs in the alloy with Sr substitution of 0.1. The magnetization value for Sr substitution is 0.3 higher than for other alloys.
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La(1-x)Sr(x)MnO3 合金的制备、合成与表征
通过将铁磁性材料植入肿瘤组织,磁性微粒已被用于热疗。La(1-x)Sr(x)MnO3在环境温度下具有较高的磁性,且居里温度易于调节,因此是热疗的最佳候选材料之一。本研究采用球磨技术合成了 La(1-x)Sr(x)MnO3 。球磨处理后还进行了多次热处理。研究人员进行了各种研究,包括 SEM-EDS、XRD、DSC 和 VSM。从 LaMnO3 和 La0.9Sr0.1MnO3 在 32.376 角和 32.706 角处的衍射图样来看,它们与数据库中的衍射图样截然不同。在 La0.9Sr0.1MnO3 中,这两个峰的距离越来越远。与 La0.7Sr0.3MnO3 和 La0.5Sr0.5MnO3 的衍射图样相反,在 32.376 角度处,强度有所下降。Sr 取代量为 0.3 的合金的比热容大于未取代的合金,而 Sr 取代量为 0.1 的合金的比热容最低。Sr 替代合金的磁化值比其他合金高 0.3。
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