Bacterial and corrosion resistance of polytetrafluoroethylene-silver composite coatings by magnetron sputtering

Haiwen Li, Zhiwen He, Wei Wu, Long Zheng, Qingfang Xu, Tenghua Gao, Song Zhang, Honglian Dai, Takashi Goto, Rong Tu
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Abstract

Titanium alloy and stainless steel implants have been widely applied in orthopedics. However, harmful ions released from implant corrosion caused by human body fluids and bacterial infections may inhibit patients’ recovery. In this work, a polytetrafluoroethylene-silver composite coating was prepared by RF unbalanced magnetron sputtering to improve the bacterial and corrosion resistance of the SS316L. The removal rates of the composite coatings for Escherichia coli and Staphylococcus aureus reached 97.27% and 99.99%, respectively. The contact angle of 131.5° and fluorescence staining experiments show that the composite coating has an antiadhesive effect on bacteria and less cytotoxicity against osteoblasts. The corrosion voltage of the composite coating was much higher than that of the control SS316L substrate, and the corrosion current density was reduced to 1/3, implying the enhancement of the corrosion resistance of the SS316L substrate.
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磁控溅射聚四氟乙烯-银复合涂层的抗菌和耐腐蚀性能
钛合金和不锈钢植入物已广泛应用于整形外科。然而,人体体液和细菌感染造成的植入物腐蚀释放出的有害离子可能会影响患者的康复。本研究采用射频不平衡磁控溅射法制备了聚四氟乙烯-银复合涂层,以提高 SS316L 的抗菌性和耐腐蚀性。复合涂层对大肠杆菌和金黄色葡萄球菌的去除率分别达到 97.27% 和 99.99%。131.5° 的接触角和荧光染色实验表明,复合涂层对细菌有抗粘附作用,对成骨细胞的细胞毒性较小。复合涂层的腐蚀电压远高于对照的 SS316L 基材,腐蚀电流密度降低到 1/3,这意味着 SS316L 基材的耐腐蚀性增强了。
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