Shuqin Zhang, Kening Zhang, Yi Liu, Dajun Ren, Xiaoqing Zhang
{"title":"Study on Modified Loaded Chitosan Adsorbent Based on Mercapto-alkenyl Click Reaction and Adsorption of Pb(II)","authors":"Shuqin Zhang, Kening Zhang, Yi Liu, Dajun Ren, Xiaoqing Zhang","doi":"10.3103/S1063455X24030111","DOIUrl":null,"url":null,"abstract":"<p>Industrialization has caused serious heavy metal pollution in water resources, which is harmful to human health. It is of great significance to use heavy metal removal technology to ensure water safety. In this study, a new kaolin/chitosan composite (TGL-CS) was prepared for the adsorption of lead-containing wastewater based on the mercapto-alkenyl base reaction strategy. The effects of pH, adsorbent dosage and ionic strength on the adsorption performance of TGL-CS were investigated. The adsorption process of Pb(II) on TGL-CS is consistent with the Langmuir isotherm and pseudo-second-order kinetic model. The maximum adsorption capacity of TGL-CS for Pb(II) was 87.72 mg/g. The adsorption mechanism of TGL-CS is mainly the coordination between Pb(II) and hydroxyl, amino and sulfur-containing groups. In particular, the click chemical reaction does not consume the amino group in chitosan but also introduces the sulfur-containing group to improve the adsorption capacity of heavy metals. In addition, the ionic strength in the environment system has little effect on the adsorption of Pb(II) by TGL-CS, and the reusability of TGL-CS is high. In summary, TGL-CS has the advantages of low cost, simple preparation, and broad application prospects in the treatment of heavy metal-polluted water bodies.</p>","PeriodicalId":680,"journal":{"name":"Journal of Water Chemistry and Technology","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Water Chemistry and Technology","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.3103/S1063455X24030111","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Industrialization has caused serious heavy metal pollution in water resources, which is harmful to human health. It is of great significance to use heavy metal removal technology to ensure water safety. In this study, a new kaolin/chitosan composite (TGL-CS) was prepared for the adsorption of lead-containing wastewater based on the mercapto-alkenyl base reaction strategy. The effects of pH, adsorbent dosage and ionic strength on the adsorption performance of TGL-CS were investigated. The adsorption process of Pb(II) on TGL-CS is consistent with the Langmuir isotherm and pseudo-second-order kinetic model. The maximum adsorption capacity of TGL-CS for Pb(II) was 87.72 mg/g. The adsorption mechanism of TGL-CS is mainly the coordination between Pb(II) and hydroxyl, amino and sulfur-containing groups. In particular, the click chemical reaction does not consume the amino group in chitosan but also introduces the sulfur-containing group to improve the adsorption capacity of heavy metals. In addition, the ionic strength in the environment system has little effect on the adsorption of Pb(II) by TGL-CS, and the reusability of TGL-CS is high. In summary, TGL-CS has the advantages of low cost, simple preparation, and broad application prospects in the treatment of heavy metal-polluted water bodies.
期刊介绍:
Journal of Water Chemistry and Technology focuses on water and wastewater treatment, water pollution monitoring, water purification, and similar topics. The journal publishes original scientific theoretical and experimental articles in the following sections: new developments in the science of water; theoretical principles of water treatment and technology; physical chemistry of water treatment processes; analytical water chemistry; analysis of natural and waste waters; water treatment technology and demineralization of water; biological methods of water treatment; and also solicited critical reviews summarizing the latest findings. The journal welcomes manuscripts from all countries in the English or Ukrainian language. All manuscripts are peer-reviewed.