Deactivation of layered MnO2 catalyst during room temperature formaldehyde degradation and its thermal regeneration mechanism

Abstract

Layered δ-MnO₂ prepared by a one-step redox method was shown to be deactivated during oxidation of formaldehyde at room temperature. Recovery of the formaldehyde degradation activity was investigated after thermal regeneration at different temperatures. XRD, SEM, TEM, H₂-TPR, XPS, TGA and DRIFTS characterization were used to analyze the physical properties of fresh, deactivated and thermally regenerated catalysts. The results showed that deactivation of catalyst was caused by less oxygen vacancies due to increased Mn⁴⁺ content during formaldehyde degradation and formation of formate blocking active sites. Thermal regeneration helped to decompose formate at the catalyst surface, restoring some of the active sites. Interplanar spacing of MnO₂ became wider and the number of Mn³⁺ on exposed crystal faces increased. More oxygen vacancies were formed. The activity of deactivated catalyst was restored. Formaldehyde degradation rate of catalyst regenerated at 200 °C remained above 80 % after 6 h, demonstrating the possibility of waste layered catalyst recycling.