{"title":"Adsorption-driven reverse osmosis separation of ethanol/water using zeolite nanosheets†","authors":"Yen-Yung Wu and Li-Chiang Lin","doi":"10.1039/D4CP01830C","DOIUrl":null,"url":null,"abstract":"<p >Developing more energy-efficient and cost-effective membrane processes for the separation of ethanol and water represents a strategically important direction to facilitate the production of renewable biofuels. In this study, by employing state-of-the-art molecular simulations, the potential of zeolite nanosheets as reverse osmosis (RO) membranes in ethanol/water separation is investigated. These materials are predicted to offer unprecedentedly high fluxes and more importantly, the ethanol-to-water separation factor can be as large as approximately 800 if the structure is meticulously selected. The separation achieved herein can in fact be considered counter-intuitive as the membrane allows the larger ethanol molecules to permeate through while blocking smaller water molecules. Further investigations reveal that the observed selectivity is strongly correlated with the adsorption selectivity of the bulk materials, suggesting an adsorption-driven mechanism. Promising candidates also appear to have the largest cavity diameter of approximately 6 Å, a size that can be commensurate with the dimensions of ethanol to facilitate its adsorption. The hydrophilicity on the membrane surfaces is as well found to play a non-negligible role. Overall, this study demonstrates the great promise of zeolite nanosheets as RO membranes for extracting anhydrous ethanol from its aqueous mixture and provides guidance toward the selection of promising membrane candidates.</p>","PeriodicalId":99,"journal":{"name":"Physical Chemistry Chemical Physics","volume":null,"pages":null},"PeriodicalIF":2.9000,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Chemistry Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/cp/d4cp01830c","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Developing more energy-efficient and cost-effective membrane processes for the separation of ethanol and water represents a strategically important direction to facilitate the production of renewable biofuels. In this study, by employing state-of-the-art molecular simulations, the potential of zeolite nanosheets as reverse osmosis (RO) membranes in ethanol/water separation is investigated. These materials are predicted to offer unprecedentedly high fluxes and more importantly, the ethanol-to-water separation factor can be as large as approximately 800 if the structure is meticulously selected. The separation achieved herein can in fact be considered counter-intuitive as the membrane allows the larger ethanol molecules to permeate through while blocking smaller water molecules. Further investigations reveal that the observed selectivity is strongly correlated with the adsorption selectivity of the bulk materials, suggesting an adsorption-driven mechanism. Promising candidates also appear to have the largest cavity diameter of approximately 6 Å, a size that can be commensurate with the dimensions of ethanol to facilitate its adsorption. The hydrophilicity on the membrane surfaces is as well found to play a non-negligible role. Overall, this study demonstrates the great promise of zeolite nanosheets as RO membranes for extracting anhydrous ethanol from its aqueous mixture and provides guidance toward the selection of promising membrane candidates.
期刊介绍:
Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions.
The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.