{"title":"Excitation of long-lived nuclear spin order using spin-locking: a geometrical formalism","authors":"Manjeet Mudgil and Narayanan D. Kurur","doi":"10.1039/D4CP01995D","DOIUrl":null,"url":null,"abstract":"<p >Over the last two decades, numerous pulse sequences have been introduced for the excitation of long-lived spin order (LLS) in high fields. The long continuous wave (CW) or adiabatic pulses used in the SLIC and APSOC sequences should remind one of the spin-locking pulses that are used to induce cross-polarization (CP). Dynamics during these spin-lockings in CP experiments are explained through a geometrical formalism. However, the SLIC and APSOC sequences are described in terms of the energy-level picture or in the language of level anti-crossings. Motivated by this analogy, this work presents here a geometrical formalism for the LLS excitation by spin-locking pulses in weakly coupled systems. The formalism is similar to the one used for CP dynamics and reveals new pulse sequences involving CW or adiabatic locking. A similar formalism for the sustaining period of LLS is also provided, which reveals new features of the dynamics and suggests the usage of modulated spin-lockings for proper LLS sustaining. For strong and intermediate regimes, although a simple geometrical formalism seems infeasible, a new pulse sequence that employs a ramp-down adiabatic pulse for both LLS excitation and reconversion to observables in both these regimes is presented here. Given the similarities between LLS excitation and well-developed CP, it may be anticipated that this work would initiate the search for new LLS excitation methods and applications.</p>","PeriodicalId":99,"journal":{"name":"Physical Chemistry Chemical Physics","volume":null,"pages":null},"PeriodicalIF":2.9000,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Chemistry Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/cp/d4cp01995d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Over the last two decades, numerous pulse sequences have been introduced for the excitation of long-lived spin order (LLS) in high fields. The long continuous wave (CW) or adiabatic pulses used in the SLIC and APSOC sequences should remind one of the spin-locking pulses that are used to induce cross-polarization (CP). Dynamics during these spin-lockings in CP experiments are explained through a geometrical formalism. However, the SLIC and APSOC sequences are described in terms of the energy-level picture or in the language of level anti-crossings. Motivated by this analogy, this work presents here a geometrical formalism for the LLS excitation by spin-locking pulses in weakly coupled systems. The formalism is similar to the one used for CP dynamics and reveals new pulse sequences involving CW or adiabatic locking. A similar formalism for the sustaining period of LLS is also provided, which reveals new features of the dynamics and suggests the usage of modulated spin-lockings for proper LLS sustaining. For strong and intermediate regimes, although a simple geometrical formalism seems infeasible, a new pulse sequence that employs a ramp-down adiabatic pulse for both LLS excitation and reconversion to observables in both these regimes is presented here. Given the similarities between LLS excitation and well-developed CP, it may be anticipated that this work would initiate the search for new LLS excitation methods and applications.
期刊介绍:
Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions.
The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.