Stimuli-Responsive Delivery of Ions through Layered Materials-Based Triangular Nanofluidic Device

Abstract

The elegance and accuracy of biological ion channels inspire the fabrication of artificial devices with similar properties. Here, we report the fabrication of iontronic devices capable of delivering ions at the nanomolar (nmol) level of accuracy. The triangular nanofluidic device prepared with reconstructed vanadium pentoxide (VO) membranes of thickness 45 ± 5.5 μm can continuously deliver K⁺, Na⁺, and Ca²⁺ ions at the rate of 0.44 ± 0.24, 0.35 ± 0.06, and 0.03 nmol/min, respectively. The ionic flow rate can be further tuned by modulating the membrane thickness and salt concentration at the source reservoir. The triangular VO device can also deliver ions in minuscule doses (∼132 ± 9.7 nmol) by electrothermally heating (33 °C) with a nichrome wire (NW) or applying light of specific intensities. The simplicity of the fabrication process of reconstructed layered material-based nanofluidic devices allows the design of complicated iontronic devices such as the three-terminal-Ni-VO (3T-Ni-VO) devices.