Adam Mizera, Sylwia Zięba, Michał Bielejewski, Alina T. Dubis and Andrzej Łapiński
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引用次数: 0
Abstract
The charge carriers in conducting pyrrole-co-poly(pyrrole-3-carboxylic) were examined using high-pressure Raman spectroscopy. The molecular structure of the new copolymer was investigated using high-resolution 13C ssNMR, 1H–13C 2D NMR correlation spectroscopy, and density functional theory (DFT) calculations. Bands in Raman spectra that showed the presence of polarons and bipolarons were studied. It was observed that the quantity of polarons and bipolarons correlated with the hydrostatic pressure. At a pressure of 4 GPa, an anomaly in the correlation between pressure and the position of the Raman band was identified.
期刊介绍:
Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions.
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