Springtail-Inspired Hierarchically Structured Polymer Films as Omniphobic Coatings for Directional Transportation of Liquids

IF 5.3 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY ACS Applied Nano Materials Pub Date : 2024-06-18 DOI:10.1021/acsanm.4c02117
Yu-Zhe Ye, Shin-Hua Lin, Shang-Yu Hsieh, Bo-Han Zeng, Han-Yu Hsueh, Chia-Feng Lin, Ya-Lien Cheng, Hsiang-Wen Hsuen, Kun-Yi Andrew Lin*, Rong-Ho Lee and Hongta Yang*, 
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Abstract

Slender springtails (Entomobrya nivalis) and orange springtails (Neanura muscorum) are capable of repelling water and organic liquids using the hexagonally arranged nanoscale waxy protrusions and microscale wrinkles on their cuticles to protect the skin-breathing arthropods against suffocation in diversified survival environments. The omniphobic hierarchical structures can even shed and directionally transport liquids along the longitudinal direction of the wrinkles. Bioinspired by springtails, monolayer colloidal crystals are self-assembled onto anisotropic microwrinkled substrates and serve as structural templates to pattern antiwetting hierarchical structure arrays. The dependence of structure configuration on the antiwetting performances is systematically investigated in this study. Impressively, the optimized structure array exhibits anisotropic omniphobic sliding characteristics toward liquids with varied surface tensions ranging from 72.8 to 27.2 mN/m. The springtail-inspired coatings undoubtedly have great potential for developing innovative applications that require directional transportation and the collection of liquids.

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受春尾启发的分层结构聚合物薄膜作为液体定向输送的疏水性涂层
纤细春尾虫(Entomobrya nivalis)和橙春尾虫(Neanura muscorum)能够利用其角质层上六角形排列的纳米级蜡质突起和微米级皱纹排斥水和有机液体,从而保护皮肤呼吸节肢动物在多样化的生存环境中免受窒息。这种全疏的分层结构甚至可以沿皱纹的纵向脱落和定向输送液体。受春蜱的生物启发,单层胶体晶体被自组装到各向异性的微皱纹基底上,并作为结构模板,形成防湿分层结构阵列。本研究系统地探讨了结构配置对防湿性能的影响。令人印象深刻的是,优化后的结构阵列对表面张力在 72.8 至 27.2 mN/m 之间的液体具有各向异性的全疏滑动特性。在开发需要定向输送和收集液体的创新应用方面,受弹簧尾翼启发的涂层无疑具有巨大的潜力。
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来源期刊
CiteScore
8.30
自引率
3.40%
发文量
1601
期刊介绍: ACS Applied Nano Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics and biology relevant to applications of nanomaterials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important applications of nanomaterials.
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