Active nematic-isotropic interfaces on flat surfaces: Effects of anchoring, ordering field and activity

IF 5.4 1区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY GIANT Pub Date : 2024-06-22 DOI:10.1016/j.giant.2024.100309
Rodrigo C.V. Coelho , José A. Moreira , Duarte M.C. Pedro , Margarida M. Telo da Gama
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Abstract

A surface in contact with the isotropic phase of a passive liquid crystal can induce nematic order over distances that range from microscopic to macroscopic when the nematic-isotropic interface undergoes an orientational-wetting transition. If the nematic is active, what happens to the interface? Does it propagate and, if it does, is its structure different from the passive one? In this paper, we address these questions. We investigate how the active nematic-isotropic interface is affected by the anchoring strength of the surface, the bulk ordering field and the activity. We find that while passive interfaces are one-dimensional the active ones exhibit two dynamical regimes: a passive-like regime and a propagating regime where the interfaces propagate until the entire domain is active nematic. Active interfaces break the translational symmetry within the interfacial plane above a threshold activity, where the active nematic fluctuations, which are ultimately responsible for the emergence of an active turbulent nematic phase, drive non-steady dynamical interfacial regimes.

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平面上的活性向列-各向同性界面:锚定、有序场和活性的影响
当向列-各向同性界面发生取向-润湿转变时,与被动液晶各向同性相接触的表面可以在从微观到宏观的距离上诱导向列有序。如果向列是活跃的,界面会发生什么变化?它是否会传播,如果传播,其结构是否与被动界面不同?在本文中,我们将探讨这些问题。我们研究了活性向列-各向同性界面如何受到表面锚定强度、体有序场和活性的影响。我们发现,被动界面是一维的,而主动界面则表现出两种动力学状态:一种是类似被动的状态,另一种是界面传播状态,即界面传播直至整个域都是主动向列。活性界面在活性阈值以上打破了界面平面内的平移对称性,活性向列波动最终导致了活性湍流向列相的出现,并推动了非稳定的动态界面机制。
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来源期刊
GIANT
GIANT Multiple-
CiteScore
8.50
自引率
8.60%
发文量
46
审稿时长
42 days
期刊介绍: Giant is an interdisciplinary title focusing on fundamental and applied macromolecular science spanning all chemistry, physics, biology, and materials aspects of the field in the broadest sense. Key areas covered include macromolecular chemistry, supramolecular assembly, multiscale and multifunctional materials, organic-inorganic hybrid materials, biophysics, biomimetics and surface science. Core topics range from developments in synthesis, characterisation and assembly towards creating uniformly sized precision macromolecules with tailored properties, to the design and assembly of nanostructured materials in multiple dimensions, and further to the study of smart or living designer materials with tuneable multiscale properties.
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