Hypergolic Propellants Based on High-Test Hydrogen Peroxide and Organic Compounds

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED Russian Journal of Applied Chemistry Pub Date : 2024-06-10 DOI:10.1134/S1070427223100014
Sh. L. Guseinov, S. G. Fedorov, V. A. Kosykh, V. A. Vaulin
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Abstract

The results of studies on determination of the ignition delay time of hypergolic low-toxicity (“green”) propellants with high-test hydrogen peroxide as an oxidizer are discussed. The use of liquid and solid fuels containing compounds that catalyze the hydrogen peroxide decomposition (manganese and copper salts) or actively react with hydrogen peroxide (e.g., NaBH4) allows preparation of propellants with the ignition delay time shorter than 20 ms, which allows using these propellants in liquid or hybrid rocket engines. The use of ionic liquids as a fuel in most cases also requires introducing promoters.

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基于耐高温过氧化氢和有机化合物的超醇推进剂
摘要 讨论了确定以高浓度过氧化氢为氧化剂的双酚低毒性("绿色")推进剂的点火延迟时间的研究结果。使用含有催化过氧化氢分解的化合物(锰盐和铜盐)或与过氧化氢发生活性反应的化合物(如 NaBH4)的液体和固体燃料,可以制备点火延迟时间小于 20 毫秒的推进剂,从而可以在液体或混合火箭发动机中使用这些推进剂。在大多数情况下,使用离子液体作为燃料还需要引入促进剂。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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