A New Polymorph of tert-Butyl (2-Aminophenyl)Carbamate

IF 0.4 4区 化学 Q4 CRYSTALLOGRAPHY Journal of Chemical Crystallography Pub Date : 2024-06-17 DOI:10.1007/s10870-024-01021-6
Zoe E. Potter, Max T. Hill, Jonathan D. Sellars, Paul G. Waddell
{"title":"A New Polymorph of tert-Butyl (2-Aminophenyl)Carbamate","authors":"Zoe E. Potter,&nbsp;Max T. Hill,&nbsp;Jonathan D. Sellars,&nbsp;Paul G. Waddell","doi":"10.1007/s10870-024-01021-6","DOIUrl":null,"url":null,"abstract":"<div><p>A new polymorph of <i>tert</i>-butyl (2-aminophenyl)carbamate was identified using single crystal X-ray diffraction. The compound crystallised in the centrosymmetric, monoclinic space group <i>P</i>2<sub>1</sub>/<i>n</i> with an asymmetric unit comprising two crystallographically-independent molecules (Zʹ = 2). This new structure was compared to that of the known polymorph with the differences between the two being attributed to a combination of space group symmetry, conformational variation, hydrogen bonding network dimensionality and crystal packing.</p></div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"54 4","pages":"285 - 290"},"PeriodicalIF":0.4000,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10870-024-01021-6.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Crystallography","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10870-024-01021-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0

Abstract

A new polymorph of tert-butyl (2-aminophenyl)carbamate was identified using single crystal X-ray diffraction. The compound crystallised in the centrosymmetric, monoclinic space group P21/n with an asymmetric unit comprising two crystallographically-independent molecules (Zʹ = 2). This new structure was compared to that of the known polymorph with the differences between the two being attributed to a combination of space group symmetry, conformational variation, hydrogen bonding network dimensionality and crystal packing.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
(2-氨基苯基)氨基甲酸叔丁酯的一种新的多聚物
利用单晶 X 射线衍射法发现了一种新的 (2-aminophenyl)carbamate 叔丁基多晶体。该化合物在中心对称的单斜空间群 P21/n 中结晶,其不对称单元由两个晶体学上独立的分子组成(Zʹ = 2)。将这种新结构与已知的多晶体结构进行了比较,发现两者之间的差异是由空间群对称性、构象变化、氢键网络尺寸和晶体堆积等因素共同造成的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
1.50
自引率
12.50%
发文量
56
审稿时长
6.3 months
期刊介绍: Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.
期刊最新文献
The Versatility of the Dicyanamide Anion (Dca) as a Bridging Ligand: Synthesis, Structure and Theory of a Unique Ladder Chain Consisting of 2 µ1,5-dca Bridged Dinuclear Cu2(dca)2 Units with Additional µ1,3-dca Bridges Along the Chain Synthesis, Crystal Structure and Fluorescent Property of a Novel Cd(II) Coordination Polymer based on Nitrogen-Containing Ligands Synthesis and Crystal Structures of Ferrocenylamine Alcohols of Ferrocenylformaldehyde with Aminoalcohols Solvent-Free Synthesis, Crystal Structure and Molecular Docking of N-(2-Hydroxyethyl) Piperazinum Chloride with Selected Biological Proteins Molecular and Crystal Structures of Some Bromocymantrenes
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1