Performance and mildness of alkyl glycoside hydroxypropyl sulfonate

IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Journal of Surfactants and Detergents Pub Date : 2024-06-27 DOI:10.1002/jsde.12781
Kuan Chang, Baotong Jia
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Abstract

Alkyl glycoside hydroxypropyl sulfonate (APGSHS), as a kind of anionic surfactant was successfully prepared using sodium 3‐chloro‐2‐hydroxypropane sulfonate and alkyl polyglucoside (APG). The surface and application properties of APGSHS were studied in detail. The results showed that APGSHS showed much enhanced solubility and there for better foaming and detergency properties than APG due to the introduction of sulfonate group. Then, the mildness of APGSHS and commercially available mild surfactants was compared using zein test and hemolysis of red blood cells (RBC) test. APGSHS has higher mildness than other surfactants, such as potassium lauroylglycinate (PLG), lauramidopropyl betaine (LAB), and sodium laurylmethyl taurate (LMT). The mechanism of mildness was investigated by studying the interaction between APGSHS and protein using zein model through micelle behavior and protein structure. It was observed that compared to other anionic surfactants such as sodium fatty alcohol polyoxyethylene ether sulfate (AES) and sodium dodecyl sulfate (SDS), APGSHS possesses a larger hydrophilic head group and causes less damage to the secondary structure of zein. Finally, the effect of different surfactants on the hair keratin loss during washing was evaluated. The results showed APGSHS had a minimal damaging effect on keratin in the hair, resulting in the lowest protein loss. This work suggests APGSHS as a promising ingredient for green and mild cleaning products.
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烷基糖苷羟丙基磺酸盐的性能和温和性
利用 3-氯-2-羟基丙烷磺酸钠和烷基聚葡萄糖苷(APG)成功制备了一种阴离子表面活性剂--烷基糖苷羟丙基磺酸盐(APGSHS)。对 APGSHS 的表面和应用特性进行了详细研究。结果表明,由于引入了磺酸基团,APGSHS 的溶解性大大提高,其发泡和去污性能也优于 APG。然后,使用玉米蛋白试验和红细胞(RBC)溶血试验比较了 APGSHS 和市售温和型表面活性剂的温和性。与月桂酰甘氨酸钾(PLG)、月桂酰胺丙基甜菜碱(LAB)和月桂甲基牛磺酸钠(LMT)等其他表面活性剂相比,APGSHS 具有更高的温和性。通过胶束行为和蛋白质结构,使用玉米蛋白模型研究了 APGSHS 与蛋白质之间的相互作用,从而研究了其温和性的机理。结果表明,与脂肪醇聚氧乙烯醚硫酸钠(AES)和十二烷基硫酸钠(SDS)等其他阴离子表面活性剂相比,APGSHS 具有较大的亲水性头基,对玉米蛋白二级结构的破坏较小。最后,还评估了不同表面活性剂对洗发过程中头发角蛋白脱落的影响。结果表明,APGSHS 对头发角蛋白的破坏作用最小,导致蛋白质损失最少。这项研究表明,APGSHS 是一种很有前景的绿色温和清洁产品成分。
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来源期刊
Journal of Surfactants and Detergents
Journal of Surfactants and Detergents 工程技术-工程:化工
CiteScore
3.80
自引率
6.20%
发文量
68
审稿时长
4 months
期刊介绍: Journal of Surfactants and Detergents, a journal of the American Oil Chemists’ Society (AOCS) publishes scientific contributions in the surfactants and detergents area. This includes the basic and applied science of petrochemical and oleochemical surfactants, the development and performance of surfactants in all applications, as well as the development and manufacture of detergent ingredients and their formulation into finished products.
期刊最新文献
Issue Information Cloning, purification, and functional characterization of recombinant pullulanase from Bacillus cereusATCC 14579 for improved detergent performance Special Issue: Glycolipid biosurfactants: Synthesis, properties, and applications Synthesis and properties of sodium stearyl polyoxypropylene acetates Study on the Pickering emulsions stabilized by SiO2 nanoparticles for enhanced oil recovery
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