Techno-economic assessment of aluminum as a clean energy carrier to decarbonize remote industries†

IF 3.2 Q2 CHEMISTRY, PHYSICAL Energy advances Pub Date : 2024-07-03 DOI:10.1039/D4YA00151F
Pascal Boudreau, Michael Johnson and Jeffrey M. Bergthorson
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Abstract

The energy sector is transitioning to a low-carbon era requiring the wide use of renewable energy sources, mainly wind and solar. In this context, aluminum could serve as a sustainable energy carrier as it stores energy in a safe and compact way. It could be used to help decarbonize remote communities and industries, trade energy on a global scale, or provide seasonal energy storage. The Hall–Héroult process, reducing aluminum oxides to aluminum, is already a technology deployed at an industrial scale. The maturity of this industry could therefore be leveraged to store electricity. To convert aluminum back to power, it can be fully oxidized with high-temperature liquid water. The hydrogen and high-temperature heat produced can then be converted to power using a combination of heat engines and/or fuel cells. For this concept to be viable, the oxides produced must be collected and reduced in a sustainable way. In this work, aluminum recharging costs were evaluated by reviewing the current reduction process and the literature available on the development of inert anodes, a technology enabling carbon-free smelting. Results show that aluminum can be cost-competitive on a chemical energy basis with most common hydrogen carriers discussed in the literature. To contextualize the findings, a remote mine case study integrates transportation, storage and power generation costs for aluminum, compared to liquefied hydrogen and ammonia. The analysis reveals that aluminum is comparable to other carbon-free solutions, although they all currently remain more expensive than diesel fuel at an input electricity price of $30/MWhe. Aluminum emerges as marginally more expensive than the direct use of ammonia, while avoiding concerns related to toxicity and NOx emissions. This study thus positions aluminum as a promising energy carrier that merits further consideration in various other applications.

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铝作为清洁能源载体实现偏远地区工业去碳化的技术经济评估
能源行业正在向低碳时代过渡,需要广泛使用可再生能源,主要是风能和太阳能。在这种情况下,铝可以作为一种可持续的能源载体,因为它能以安全、紧凑的方式储存能源。它可用于帮助偏远社区和工业去碳化,在全球范围内进行能源交易,或提供季节性能源储存。将铝氧化物还原成铝的霍尔-赫鲁特工艺已经是一项工业规模的技术。因此,可以利用这一行业的成熟性来储存电力。要将铝重新转化为电能,可以用高温液态水将其完全氧化。产生的氢气和高温热量可通过热机和/或燃料电池组合转化为电力。要使这一概念可行,必须以可持续的方式收集和还原产生的氧化物。在这项工作中,通过审查当前的还原工艺和有关开发惰性阳极(一种实现无碳冶炼的技术)的文献,对铝的再充电成本进行了评估。结果表明,就化学能而言,铝的成本与文献中讨论的大多数常见氢载体相比具有竞争力。为了说明研究结果的来龙去脉,一项偏远矿山案例研究将铝的运输、储存和发电成本与液化氢和氨进行了综合比较。分析表明,铝与其他无碳解决方案不相上下,尽管在输入电价为 30 美元/兆瓦时,铝的成本仍高于柴油。与直接使用氨气相比,铝的成本略高,同时避免了与毒性和氮氧化物排放相关的问题。因此,本研究将铝定位为一种有前途的能源载体,值得在其他各种应用中进一步考虑。
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