Ternary nitride GaFe3N: Study of the structural and glassy magnetic properties at low temperatures

IF 3.5 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of the American Ceramic Society Pub Date : 2024-06-22 DOI:10.1111/jace.19973
Wei Wang, Yongkun Wang, Yehan Yan, Pengzhen He, Guanglin Wang, Lei Bao, Houbao Liu, Xucai Kan
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Abstract

In ternary nitrides, the Ga0.9Fe3.1N sample has ultimately been prepared through solid‐gas preparation for the gallium‐richest phase GaFe3N. The substitution of gallium atoms for iron atoms weakens the saturation magnetization of ferromagnetic γʹ‐Fe4N and induces the transmission from ferromagnetism to antiferromagnetism. A new magnetic behavior, defined as the spin glassy magnetic state, has been observed in the temperature‐dependent magnetic performance measurement process for Ga0.9Fe3.1N. The magnetic competition between ferromagnetic and antiferromagnetic Fe–Fe bonds will lead to the spin frustration of the magnetic system. And even the positional disorders caused by substitution, will all be responsible for the spin glassy behavior in Ga0.9Fe3.1N.
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三元氮化物 GaFe3N:低温下的结构和玻璃磁性能研究
在三元氮化物中,Ga0.9Fe3.1N 样品最终是通过固气制备法制备出最富镓相 GaFe3N 的。用镓原子代替铁原子削弱了铁磁性γʹ-Fe4N的饱和磁化,并诱导了从铁磁性到反铁磁性的传递。在对 Ga0.9Fe3.1N 进行随温度变化的磁性能测量过程中,观察到了一种新的磁性行为,即自旋玻璃磁态。铁磁性和反铁磁性 Fe-Fe 键之间的磁性竞争将导致磁性系统的自旋沮度。甚至由置换引起的位置紊乱也会导致 Ga0.9Fe3.1N 的自旋玻璃化行为。
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来源期刊
Journal of the American Ceramic Society
Journal of the American Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
7.50
自引率
7.70%
发文量
590
审稿时长
2.1 months
期刊介绍: The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.
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