Jiongyang Qi, Zilong Liu, Zihan Zhao, Zhiyuan Tan, Fangfei Liu, Nan Liu
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引用次数: 0
Abstract
Ionogels have gained increasing attention in the field of flexible electronic devices. However, it is a huge challenge to prepare ionogels with high toughness and adhesive property. In this study, we present a straightforward approach to fabricating tough and reusable ionogel adhesives by randomly copolymerizing two monomers with varying solubilities in an ionic liquid solvent. Specifically, acrylamide (AM) and methacryloxyethyltrimethylammonium bis(trifluoromethanesulfonyl)imide ([MATAC][TFSI]) are copolymerized in situ in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][TFSI]) to form phase-separated ionogels, wherein the hydrogen-bond-rich phases and solvent-rich phases contribute to enhancing toughness. The abundant noncovalent interactions provide the robust internal cohesive force, which provides ionogels a stable adhesion ability during the cyclic adhesion–peeling process. The resulting ionogel adhesive exhibits elevated fracture strength (2.75 MPa), impressive toughness (9.58 MJ/m3), non-disposable adhesiveness (0.692 MPa), and exceptional environmental stability. Moreover, the sensor prepared by ionogel adhesives demonstrates fatigue resistance and a wide detection range, thus holding potential for the development of advanced and sustainable flexible electronic devices.
期刊介绍:
ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers.
The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.